Advancements in Biomass Recalcitrance: The Use of Lignin for the Production of Fuels and Chemicals PDF Download
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Author: Arthur J. Ragauskas Publisher: Frontiers Media SA ISBN: 2889457060 Category : Languages : en Pages : 103
Book Description
Lignocellulosic biomass has great potentials as an alternative feedstock for fuels and chemicals. For effective utilization of biomass, biomass recalcitrance, which is inherent resistance of plant cell walls to biological deconstruction, needs to be reduced. Among many factors in biomass, lignin is significantly related to biomass recalcitrance. Lignin, a complex aromatic polymer, is the largest non-carbohydrate component (15-40% dry weight) in most terrestrial plants. In nature, it provides a structural integrity, facilitates water and nutrient transport, and protects plants from microbial attack. From a different angle, lignin significantly contributes to biomass recalcitrance, so it is necessary to reduce and/or modify the lignin for effective conversion of biomass. Genetic modifications of the lignin biosynthetic pathway and lignin-targeting pretreatments have been developed to minimize the lignin-induced biomass recalcitrance. High carbon content of lignin also renders it an attractive feedstock for many applications. About 100,000 to 200,000 tons of lignin can be generated per year as a byproduct from cellulosic ethanol production, so valorization of these lignins could be one of keys for achieving economic biorefinery. However, investigations of lignin conversion have not been accomplished as the utilization of carbohydrates in biomass. Depolymerization of lignin is still challenging because of its broad distribution of bond strengths, recondensation of low-molecular species, and poor product selectivity. Diverse biological and thermochemical depolymerization methods have been investigated to overcome these barriers. In this Research Topic, recent advancements in biomass recalcitrance by effective utilization of lignin are introduced.
Author: Arthur J. Ragauskas Publisher: Frontiers Media SA ISBN: 2889457060 Category : Languages : en Pages : 103
Book Description
Lignocellulosic biomass has great potentials as an alternative feedstock for fuels and chemicals. For effective utilization of biomass, biomass recalcitrance, which is inherent resistance of plant cell walls to biological deconstruction, needs to be reduced. Among many factors in biomass, lignin is significantly related to biomass recalcitrance. Lignin, a complex aromatic polymer, is the largest non-carbohydrate component (15-40% dry weight) in most terrestrial plants. In nature, it provides a structural integrity, facilitates water and nutrient transport, and protects plants from microbial attack. From a different angle, lignin significantly contributes to biomass recalcitrance, so it is necessary to reduce and/or modify the lignin for effective conversion of biomass. Genetic modifications of the lignin biosynthetic pathway and lignin-targeting pretreatments have been developed to minimize the lignin-induced biomass recalcitrance. High carbon content of lignin also renders it an attractive feedstock for many applications. About 100,000 to 200,000 tons of lignin can be generated per year as a byproduct from cellulosic ethanol production, so valorization of these lignins could be one of keys for achieving economic biorefinery. However, investigations of lignin conversion have not been accomplished as the utilization of carbohydrates in biomass. Depolymerization of lignin is still challenging because of its broad distribution of bond strengths, recondensation of low-molecular species, and poor product selectivity. Diverse biological and thermochemical depolymerization methods have been investigated to overcome these barriers. In this Research Topic, recent advancements in biomass recalcitrance by effective utilization of lignin are introduced.
Author: Publisher: ISBN: Category : Languages : en Pages : 0
Book Description
Lignocellulosic biomass has great potentials as an alternative feedstock for fuels and chemicals. For effective utilization of biomass, biomass recalcitrance, which is inherent resistance of plant cell walls to biological deconstruction, needs to be reduced. Among many factors in biomass, lignin is significantly related to biomass recalcitrance. Lignin, a complex aromatic polymer, is the largest non-carbohydrate component (15-40% dry weight) in most terrestrial plants. In nature, it provides a structural integrity, facilitates water and nutrient transport, and protects plants from microbial attack. From a different angle, lignin significantly contributes to biomass recalcitrance, so it is necessary to reduce and/or modify the lignin for effective conversion of biomass. Genetic modifications of the lignin biosynthetic pathway and lignin-targeting pretreatments have been developed to minimize the lignin-induced biomass recalcitrance. High carbon content of lignin also renders it an attractive feedstock for many applications. About 100,000 to 200,000 tons of lignin can be generated per year as a byproduct from cellulosic ethanol production, so valorization of these lignins could be one of keys for achieving economic biorefinery. However, investigations of lignin conversion have not been accomplished as the utilization of carbohydrates in biomass. Depolymerization of lignin is still challenging because of its broad distribution of bond strengths, recondensation of low-molecular species, and poor product selectivity. Diverse biological and thermochemical depolymerization methods have been investigated to overcome these barriers. In this Research Topic, recent advancements in biomass recalcitrance by effective utilization of lignin are introduced.
Author: Publisher: Elsevier ISBN: 0128131969 Category : Reference Languages : en Pages : 4238
Book Description
Encyclopedia of Renewable and Sustainable Materials, Five Volume Set provides a comprehensive overview, covering research and development on all aspects of renewable, recyclable and sustainable materials. The use of renewable and sustainable materials in building construction, the automotive sector, energy, textiles and others can create markets for agricultural products and additional revenue streams for farmers, as well as significantly reduce carbon dioxide (CO2) emissions, manufacturing energy requirements, manufacturing costs and waste. This book provides researchers, students and professionals in materials science and engineering with tactics and information as they face increasingly complex challenges around the development, selection and use of construction and manufacturing materials. Covers a broad range of topics not available elsewhere in one resource Arranged thematically for ease of navigation Discusses key features on processing, use, application and the environmental benefits of renewable and sustainable materials Contains a special focus on sustainability that will lead to the reduction of carbon emissions and enhance protection of the natural environment with regard to sustainable materials
Author: Pradeep Verma Publisher: Springer Nature ISBN: 9811943168 Category : Sports & Recreation Languages : en Pages : 296
Book Description
This book is an attempt to provide an account of biomass recalcitrance and available physical and chemical methods for biomass pretreatment and hydrolysis. Its focuses on understanding the critical role of enzymes in the development of integrated biorefinery. The book also presents an overview of the utilization of waste biomass as a support system for enzyme immobilization for easy recovery and reuse for multiple cycles. strategies where enzymes can be used. The book also attempts to understand how enzymes can play a vital role in waste valorization for energy and biomaterial production. Further, the book will present an overview of how advanced technologies such as omics and in-silico approaches can help in understanding the chemistry affecting recalcitrance and the mechanism of enzyme catalysts in their bioconversion. An understanding of the life cycle assessment of waste biomass biorefinery will be needed before its implementation. The book will serve as additional reading material for undergraduate and graduate students of energy studies, chemical engineering, applied biotechnology, and environmental sciences. This book is of interest to academicians, scientists, environmentalists, and policymakers.
Author: Robert Henry Publisher: Frontiers Media SA ISBN: 2889198677 Category : Biotechnology Languages : en Pages : 158
Book Description
The conversion of lignocellulosic biomass into renewable fuels and other commodities has provided an appealing alternative towards supplanting global dependence on fossil fuels. The suitability of multitudes of plants for deconstruction to useful precursor molecules and products is currently being evaluated. These studies have probed a variety of phenotypic traits, including cellulose, non-cellulosic polysaccharide, lignin, and lignin monomer composition, glucose and xylose production following enzymatic hydrolysis, and an assessment of lignin-carbohydrate and lignin-lignin linkages, to name a few. These quintessential traits can provide an assessment of biomass recalcitrance, enabling researchers to devise appropriate deconstruction strategies. Plants with high polysaccharide and lower lignin contents have been shown to breakdown to monomeric sugars more readily. Not all plants contain ideal proportions of the various cell wall constituents, however. The capabilities of biotechnology can alleviate this conundrum by tailoring the chemical composition of plants to be more favorable for conversion to sugars, fuels, etc. Increases in the total biomass yield, cellulose content, or conversion efficiency through, for example, a reduction in lignin content, are pathways being evaluated to genetically improve plants for use in manufacturing biofuels and bio-based chemicals. Although plants have been previously domesticated for food and fiber production, the collection of phenotypic traits prerequisite for biofuel production may necessitate new genetic breeding schemes. Given the plethora of potential plants available for exploration, rapid analytical methods are needed to more efficiently screen through the bulk of samples to hone in on which feedstocks contain the desired chemistry for subsequent conversion to valuable, renewable commodities. The standard methods for analyzing biomass and related intermediates and finished products are laborious, potentially toxic, and/or destructive. They may also necessitate a complex data analysis, significantly increasing the experimental time and add unwanted delays in process monitoring, where delays can incur in significant costs. Advances in thermochemical and spectroscopic techniques have enabled the screening of thousands of plants for different phenotypes, such as cell-wall cellulose, non-cellulosic polysaccharide, and lignin composition, lignin monomer composition, or monomeric sugar release. Some instrumental methods have been coupled with multivariate analysis, providing elegant chemometric predictive models enabling the accelerated identification of potential feedstocks. In addition to the use of high-throughput analytical methods for the characterization of feedstocks based on phenotypic metrics, rapid instrumental techniques have been developed for the real-time monitoring of diverse processes, such as the efficacy of a specific pretreatment strategy, or the formation of end products, such as biofuels and biomaterials. Real-time process monitoring techniques are needed for all stages of the feedstocks-to-biofuels conversion process in order to maximize efficiency and lower costs by monitoring and optimizing performance. These approaches allow researchers to adjust experimental conditions during, rather than at the conclusion, of a process, thereby decreasing overhead expenses. This Frontiers Research Topic explores options for the modification of biomass composition and the conversion of these feedstocks into to biofuels or biomaterials and the related innovations in methods for the analysis of the composition of plant biomass, and advances in assessing up- and downstream processes in real-time. Finally, a review of the computational models available for techno-economic modeling and lifecycle analysis will be presented.
Author: Publisher: ISBN: Category : Languages : en Pages : 0
Book Description
The conversion of lignocellulosic biomass into renewable fuels and other commodities has provided an appealing alternative towards supplanting global dependence on fossil fuels. The suitability of multitudes of plants for deconstruction to useful precursor molecules and products is currently being evaluated. These studies have probed a variety of phenotypic traits, including cellulose, non-cellulosic polysaccharide, lignin, and lignin monomer composition, glucose and xylose production following enzymatic hydrolysis, and an assessment of lignin-carbohydrate and lignin-lignin linkages, to name a few. These quintessential traits can provide an assessment of biomass recalcitrance, enabling researchers to devise appropriate deconstruction strategies. Plants with high polysaccharide and lower lignin contents have been shown to breakdown to monomeric sugars more readily. Not all plants contain ideal proportions of the various cell wall constituents, however. The capabilities of biotechnology can alleviate this conundrum by tailoring the chemical composition of plants to be more favorable for conversion to sugars, fuels, etc. Increases in the total biomass yield, cellulose content, or conversion efficiency through, for example, a reduction in lignin content, are pathways being evaluated to genetically improve plants for use in manufacturing biofuels and bio-based chemicals. Although plants have been previously domesticated for food and fiber production, the collection of phenotypic traits prerequisite for biofuel production may necessitate new genetic breeding schemes. Given the plethora of potential plants available for exploration, rapid analytical methods are needed to more efficiently screen through the bulk of samples to hone in on which feedstocks contain the desired chemistry for subsequent conversion to valuable, renewable commodities. The standard methods for analyzing biomass and related intermediates and finished products are laborious, potentially toxic, and/or destructive. They may also necessitate a complex data analysis, significantly increasing the experimental time and add unwanted delays in process monitoring, where delays can incur in significant costs. Advances in thermochemical and spectroscopic techniques have enabled the screening of thousands of plants for different phenotypes, such as cell-wall cellulose, non-cellulosic polysaccharide, and lignin composition, lignin monomer composition, or monomeric sugar release. Some instrumental methods have been coupled with multivariate analysis, providing elegant chemometric predictive models enabling the accelerated identification of potential feedstocks. In addition to the use of high-throughput analytical methods for the characterization of feedstocks based on phenotypic metrics, rapid instrumental techniques have been developed for the real-time monitoring of diverse processes, such as the efficacy of a specific pretreatment strategy, or the formation of end products, such as biofuels and biomaterials. Real-time process monitoring techniques are needed for all stages of the feedstocks-to-biofuels conversion process in order to maximize efficiency and lower costs by monitoring and optimizing performance. These approaches allow researchers to adjust experimental conditions during, rather than at the conclusion, of a process, thereby decreasing overhead expenses. This Frontiers Research Topic explores options for the modification of biomass composition and the conversion of these feedstocks into to biofuels or biomaterials and the related innovations in methods for the analysis of the composition of plant biomass, and advances in assessing up- and downstream processes in real-time. Finally, a review of the computational models available for techno-economic modeling and lifecycle analysis will be presented.
Author: Gregg T. Beckham Publisher: Royal Society of Chemistry ISBN: 1782625542 Category : Science Languages : en Pages : 528
Book Description
A comprehensive, interdisciplinary picture of how lignocellulosic biorefineries could potentially employ lignin valorization technologies.
Author: Charles E. Wyman Publisher: John Wiley & Sons ISBN: 111856040X Category : Science Languages : en Pages : 597
Book Description
Plant biomass is attracting increasing attention as a sustainable resource for large-scale production of renewable fuels and chemicals. However, in order to successfully compete with petroleum, it is vital that biomass conversion processes are designed to minimize costs and maximize yields. Advances in pretreatment technology are critical in order to develop high-yielding, cost-competitive routes to renewable fuels and chemicals. Aqueous Pretreatment of Plant Biomass for Biological and Chemical Conversion to Fuels and Chemicals presents a comprehensive overview of the currently available aqueous pretreatment technologies for cellulosic biomass, highlighting the fundamental chemistry and biology of each method, key attributes and limitations, and opportunities for future advances. Topics covered include: • The importance of biomass conversion to fuels • The role of pretreatment in biological and chemical conversion of biomass • Composition and structure of biomass, and recalcitrance to conversion • Fundamentals of biomass pretreatment at low, neutral and high pH • Ionic liquid and organosolv pretreatments to fractionate biomass • Comparative data for application of leading pretreatments and effect of enzyme formulations • Physical and chemical features of pretreated biomass • Economics of pretreatment for biological processing • Methods of analysis and enzymatic conversion of biomass streams • Experimental pretreatment systems from multiwell plates to pilot plant operations This comprehensive reference book provides an authoritative source of information on the pretreatment of cellulosic biomass to aid those experienced in the field to access the most current information on the topic. It will also be invaluable to those entering the growing field of biomass conversion.
Author: Arthur J. Ragauskas
Author: Arthur J. Ragauskas
Author: 
Author: 
Author: Pradeep Verma
Author: Robert Henry
Author: Li Shuai
Author: 
Author: Gregg T. Beckham
Author: Timothy G. Rials
Author: Charles E. Wyman