Assessment of solar photo-fenton in raceway pond reactors for micropollutant removal in secondary effluents from agro-food industry and municipal WWWTPs PDF Download
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Author: Gracia Rivas Ibáñez Publisher: Universidad Almería ISBN: 8416642796 Category : Technology & Engineering Languages : en Pages : 242
Book Description
Existe una creciente preocupación medioambiental debida la presencia de microcontaminantes orgánicos en los sistemas acuáticos. La escasa eficiencia en la degradación de contaminantes orgánicos persistentes en las plantas de tratamiento de aguas residuales convencionales basadas en procesos biológicos constituye uno de los principales fuentes de su emisión en el medio ambiente. Esto significa la liberación continua en el ciclo del agua de sustancias que aunque se encuentran en muy bajas concentraciones, han sido reconocidas como potencialmente peligrosas para el medio ambiente y la salud humana. Por tanto, para la eliminación de estas sustancias se está investigando la inclusión de un tratamiento terciario en las estaciones depuradoras de aguas residuales. En este respecto, los procesos de oxidación avanzada (POA) han sido ampliamente investigados debido a la generación de radicales hidroxilos altamente reactivos, capaces de oxidar compuestos orgánicos. Entre ellos, el proceso foto-Fenton ha demostrado ser eficaz en la eliminación de microcontaminantes. Sin embargo, todavía se necesita investigar en la operación de este proceso para su aplicación en plantas de tratamiento de aguas residuales a escala real. Este trabajo ha sido diseñado para evaluar diferentes estrategias de operación del proceso foto-Fenton como tratamiento terciario para eliminar microcontaminantes en efluentes secundarios de la industria agroalimentaria (“Cítricos del Andarax S.A.”, Almería, España) y de plantas de tratamiento de aguas residuales municipales. La evaluación se ha realizado en función de las características de las distintas matrices de agua así como por la viabilidad de escalar el proceso a niveles reales utilizando un reactor de bajo costo tipo “raceway”. Los reactores “raceway” son fotorreactores extensivos formados por canales donde el líquido es movido por un agitador de palas y que permiten tratar grandes volúmenes de agua. En resumen, el trabajo presentado en esta tesis muestra que controlar el pH durante la depuración biológica de aguas residuales de industria agro-alimentaria facilita la eliminación de microcontaminantes mediante el proceso de foto-Fenton y que reduce los costes de reactivos. Además, el exceso de fango generado durante el tratamiento biológico puede ser reducido por ultrasonicación del fango purgado y degrada la mayoría de los plaguicidas absorbidos en el fango. Por otro lado, los reactores tipo “raceway” permiten altas capacidades de tratamiento para la eliminación de microcontaminantes mediante procesos de Fenton solares como la dosificación secuencial de hierro y el uso del complejo Fe3+/EDDS, habiendo demostrado ser tratamientos eficientes en la eliminación de microcontaminates y toxicidad en efluentes secundarios de depuradoras de aguas residuales.
Author: Gracia Rivas Ibáñez Publisher: Universidad Almería ISBN: 8416642796 Category : Technology & Engineering Languages : en Pages : 242
Book Description
Existe una creciente preocupación medioambiental debida la presencia de microcontaminantes orgánicos en los sistemas acuáticos. La escasa eficiencia en la degradación de contaminantes orgánicos persistentes en las plantas de tratamiento de aguas residuales convencionales basadas en procesos biológicos constituye uno de los principales fuentes de su emisión en el medio ambiente. Esto significa la liberación continua en el ciclo del agua de sustancias que aunque se encuentran en muy bajas concentraciones, han sido reconocidas como potencialmente peligrosas para el medio ambiente y la salud humana. Por tanto, para la eliminación de estas sustancias se está investigando la inclusión de un tratamiento terciario en las estaciones depuradoras de aguas residuales. En este respecto, los procesos de oxidación avanzada (POA) han sido ampliamente investigados debido a la generación de radicales hidroxilos altamente reactivos, capaces de oxidar compuestos orgánicos. Entre ellos, el proceso foto-Fenton ha demostrado ser eficaz en la eliminación de microcontaminantes. Sin embargo, todavía se necesita investigar en la operación de este proceso para su aplicación en plantas de tratamiento de aguas residuales a escala real. Este trabajo ha sido diseñado para evaluar diferentes estrategias de operación del proceso foto-Fenton como tratamiento terciario para eliminar microcontaminantes en efluentes secundarios de la industria agroalimentaria (“Cítricos del Andarax S.A.”, Almería, España) y de plantas de tratamiento de aguas residuales municipales. La evaluación se ha realizado en función de las características de las distintas matrices de agua así como por la viabilidad de escalar el proceso a niveles reales utilizando un reactor de bajo costo tipo “raceway”. Los reactores “raceway” son fotorreactores extensivos formados por canales donde el líquido es movido por un agitador de palas y que permiten tratar grandes volúmenes de agua. En resumen, el trabajo presentado en esta tesis muestra que controlar el pH durante la depuración biológica de aguas residuales de industria agro-alimentaria facilita la eliminación de microcontaminantes mediante el proceso de foto-Fenton y que reduce los costes de reactivos. Además, el exceso de fango generado durante el tratamiento biológico puede ser reducido por ultrasonicación del fango purgado y degrada la mayoría de los plaguicidas absorbidos en el fango. Por otro lado, los reactores tipo “raceway” permiten altas capacidades de tratamiento para la eliminación de microcontaminantes mediante procesos de Fenton solares como la dosificación secuencial de hierro y el uso del complejo Fe3+/EDDS, habiendo demostrado ser tratamientos eficientes en la eliminación de microcontaminates y toxicidad en efluentes secundarios de depuradoras de aguas residuales.
Author: Matthew A. Tarr Publisher: CRC Press ISBN: 9780203912553 Category : Science Languages : en Pages : 506
Book Description
Chemical Degradation Methods for Wastes and Pollutants focuses on established and emerging chemical procedures for the management of pollutants in industrial wastewater and the environment. This reference offers an in-depth explanation of the degradation process, mechanisms, and control factors affecting each method, as well as issues crucial to th
Author: Suresh C. Ameta Publisher: Academic Press ISBN: 0128105259 Category : Science Languages : en Pages : 430
Book Description
Advanced Oxidation Processes for Waste Water Treatment: Emerging Green Chemical Technology is a complete resource covering the fundamentals and applications of all Advanced Oxidation Processes (AOPs). This book presents the most up-to-date research on AOPs and makes the argument that AOPs offer an eco-friendly method of wastewater treatment. In addition to an overview of the fundamentals and applications, it details the reactive species involved, along with sections on reactor designs, thus helping readers understand and implement these methods. Presents in-depth coverage of all types of Advanced Oxidation Processes, including Super Critical Water Oxidation, Photo-Fenton and Like Processes Includes a fundamental review, applications, reactive species and reactor designs Reviews applications across waste types, including industrial waste, domestic and municipal sewage, and hospital wastes
Author: Marta I. Litter Publisher: CRC Press ISBN: 1315777657 Category : Science Languages : en Pages : 350
Book Description
Advanced Oxidation Technologies (AOTs) or Processes (AOPs) are relatively new and innovative technologies to remove harmful and toxic pollutants. The most important processes among them are those using light, such as UVC/H2O2, photo-Fenton and heterogeneous photocatalysis with TiO2. These technologies are also relatively low-cost and therefore usef
Author: Samira Hosseini Publisher: Springer ISBN: 981106766X Category : Technology & Engineering Languages : en Pages : 115
Book Description
This book offers comprehensive information on all aspects of ELISA, starting with the fundamentals of the immune system. It also reviews the history of analytical assays prior to the advent of ELISA (enzyme-linked immunosorbent assay) and addresses the materials of choice for the fabrication of the platforms, possible biomolecular interactions, different protocols, and evaluation parameters. The book guides readers through the respective steps of the analytical assay, while also familiarizing them with the possible sources of error in the assay. It offers detailed insights into the immobilization techniques used for protein attachment, as well as methods for evaluating the assay and calculating the key parameters, such as sensitivity, specificity, accuracy and limit of detection. In addition, the book explores the advantages and shortcomings of the conventional ELISA, as well as various approaches to improving its performance. In this regard, merging and integrating other technologies with widely known ELISAs have opened new avenues for the advancement of this immunoassay. Accordingly, the book provides cutting-edge information on integrated platforms such as ELISpot, plasmonic ELISAs, sphere-/bead-based ELISAs, paper-/fiber-based ELISAs and ELISA in micro-devices.
Author: Everett Jenne Publisher: Elsevier ISBN: 008049868X Category : Science Languages : en Pages : 583
Book Description
Adsorption of Metals by Geomedia, serves as a needed resource for this topic which has received much attention during the past 15 years. The book provides an in-depth review of the field, followed by numerouschapters that document the current status of adsorption research for a variety of metals by geomedia ranging from individual minerals to sediments and soils. Adsorption mechanisms are detailed and precipitation is presented as a distinct sorption process.Virtually all factors affecting the extent of metal adsorption are examined, including the effects of selected anions, competition among metals, pH, metal concentration, loading, variable metal adsorption capacity, ionic strength, hydrogen exchange and stoichiometry, and solids concentration. A variety of adsorption models are briefly presented and some are used to extend laboratory studies to field sites. The book is comprised of a collection of papers contributed by leading investigators from Canada, France, the Netherlands, the United Kingdom and the US. Includes a wide-ranging review of the status of adsorption research and a prospectus on future research Details all known factors affecting the extent of adsorption Covers basic adsorption equations and interrelationships Clearly documents experimental procedures Presents adsorption data for eleven metals and three other elements Uses normalization to greatly reduce apparent variability among absorbents Provides extensive literature citations and a comprehensive index
Author: Francisco J. Cervantes Publisher: IWA Publishing ISBN: 1843391147 Category : Science Languages : en Pages : 361
Book Description
Advanced Biological Treatment Processes for Industrial Wastewaters provides unique information relative to both the principles and applications of biological wastewater treatment systems for industrial effluents. Case studies document the application of biological wastewater treatment systems in different industrial sectors such as chemical, petrochemical, food-processing, mining, textile and fermentation. With more than 70 tables, 100 figures, 200 equations and several illustrations, the book provides a broad and deep understanding of the main aspects to consider during the design and operation of industrial wastewater treatment plants. Students, researchers and practitioners dealing with the design and application of biological systems for industrial wastewater treatment will find this book invaluable.
Author: Inamuddin Publisher: Materials Research Forum LLC ISBN: 194529163X Category : Technology & Engineering Languages : en Pages : 362
Book Description
Wastewater represents an alternative to freshwater if it can be treated successfully for re-use applications. Promising techniques involve photocatalysis, adsorption, nanocomposites, and membranes. The book focusses on the following topics: Effluent detoxification and degradation kinetics of organic dyes using Fenton and photo-Fenton processes. Degradation of methylene blue using nanocomposites as a potential photocatalyst. Agricultural and agro-industries based wastes as low-cost biosorbents. Use of carbon quantum dots (CQDs) for photocatalytic degradation of organic pollutants. Detection, determination and removal of phenolic compounds from wastewater. Decomposition of organic dyes via photocatalysis. Oxide-semiconductor nanomaterials for photocatalytic wastewater purification. Photocatalytic efficiency of various ZnO composites for degradation of organic pollutants. TiO2 based nanocomposites. Membrane filtration processes for the removal of organics from industrial wastewater.
Author: Mariano Mercurio Publisher: Elsevier ISBN: 0128146184 Category : Technology & Engineering Languages : en Pages : 362
Book Description
Modified Clay and Zeolite Nanocomposite Materials: Environmental and Pharmaceutical Applications retraces the most important knowledge gaps that the scientific community is facing, including a drawback of real-world applications. This valuable resource explores the novel applications of this group of nanomaterials that can be suitably surface-modified to obtain properties that can be applied in environmental and pharmaceutical fields. For example, modification with surfactants has given new motivation to the study of these materials by producing an inversion in the ion exchange behavior from cationic to anionic. This strategy has paved the way for new uses highlighted in this timely resource. Explores the combination of both minerals (clay and zeolite) together, with their application in two broad areas of emerging research Explains better utilization and applications for modified clay and zeolite through detailed comparative studies Consolidates information on the modification and tuning of clay and zeolite materials for novelty applications Helps users in the selection of materials, surface features, and other functionalization for diverse applications
Author: A. Dabrowski Publisher: Elsevier ISBN: 9780080526027 Category : Technology & Engineering Languages : en Pages : 923
Book Description
There has been a lack of authoritative, current information on the structure, investigation and preparation of inorganic sorbents, their numerous applications as well as the adsorption from gaseous and liquid phases on new and chemically modified inorganic solids. This volume deals with the above-mentioned themes and presents 34 up-to-date comprehensive and critical reviews written by well-recognized authorities. The sorbents discussed are primarily mineral ones. Each contribution treats a problem critically by showing its development, presenting documentation on the state-of-the-art and identifying subjects for further research. The book will be of interest to researchers in academic institutes and industrial laboratories engaged in the fields of surface chemistry, inorganic chemistry, adsorption, ion-exchange, catalysis, chromatography and spectroscopy of the surface phenomena, as well as to students attending graduate and postgraduate courses.
Author: Gracia Rivas Ibáñez
Author: Gracia Rivas Ibáñez
Author: Matthew A. Tarr
Author: Suresh C. Ameta
Author: Marta I. Litter
Author: Samira Hosseini
Author: Everett Jenne
Author: Francisco J. Cervantes
Author: Inamuddin
Author: Mariano Mercurio
Author: A. Dabrowski