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Author: Gregory J. Kubas Publisher: Springer Science & Business Media ISBN: 0306475979 Category : Science Languages : en Pages : 479
Book Description
According to R.H. Crabtree, Metal Dihydrogen and sigma-Bond Complexes is described as `the definitive account of twentieth-century work in the area of sigma complexation'. It covers not only Kubas' discovery of dihydrogen coordination and the study of its structure and general properties but also discusses both the theoretical beliefs and experimental results of bonding and activation of dihydrogen on metal centers and the coordination and activation of C-H, B-H, X-H, and X-Y bonds, giving an overview of `one of the hottest areas in chemistry'.
Author: Gregory J. Kubas Publisher: Springer Science & Business Media ISBN: 0306475979 Category : Science Languages : en Pages : 479
Book Description
According to R.H. Crabtree, Metal Dihydrogen and sigma-Bond Complexes is described as `the definitive account of twentieth-century work in the area of sigma complexation'. It covers not only Kubas' discovery of dihydrogen coordination and the study of its structure and general properties but also discusses both the theoretical beliefs and experimental results of bonding and activation of dihydrogen on metal centers and the coordination and activation of C-H, B-H, X-H, and X-Y bonds, giving an overview of `one of the hottest areas in chemistry'.
Author: Gregory J. Kubas Publisher: Springer ISBN: 9781475775389 Category : Science Languages : en Pages : 472
Book Description
According to R.H. Crabtree, Metal Dihydrogen and sigma-Bond Complexes is described as `the definitive account of twentieth-century work in the area of sigma complexation'. It covers not only Kubas' discovery of dihydrogen coordination and the study of its structure and general properties but also discusses both the theoretical beliefs and experimental results of bonding and activation of dihydrogen on metal centers and the coordination and activation of C-H, B-H, X-H, and X-Y bonds, giving an overview of `one of the hottest areas in chemistry'.
Author: Vladimir I. Bakhmutov Publisher: John Wiley & Sons ISBN: 9780470226742 Category : Science Languages : en Pages : 256
Book Description
This definitive reference consolidates current knowledge on dihydrogen bonding, emphasizing its role in organizing interactions in different chemical reactions and molecular aggregations. After an overview, it analyzes the differences between dihydrogen bonds, classical hydrogen bonds, and covalent bonds. It describes dihydrogen bonds as intermediates in intramolecular and intermolecular proton transfer reactions. It describes dihydrogen bonding in the solid-state, the gas phase, and in solution. This is the premier reference for physical chemists, biochemists, biophysicists, and chemical engineers.
Author: Gregory J. Kubas Publisher: Springer Science & Business Media ISBN: 0306464659 Category : Science Languages : en Pages : 479
Book Description
According to R.H. Crabtree, Metal Dihydrogen and sigma-Bond Complexes is described as `the definitive account of twentieth-century work in the area of sigma complexation'. It covers not only Kubas' discovery of dihydrogen coordination and the study of its structure and general properties but also discusses both the theoretical beliefs and experimental results of bonding and activation of dihydrogen on metal centers and the coordination and activation of C-H, B-H, X-H, and X-Y bonds, giving an overview of `one of the hottest areas in chemistry'.
Author: Maurizio Peruzzini Publisher: Elsevier ISBN: 9780080540337 Category : Science Languages : en Pages : 578
Book Description
This book has been conceived to collect the most important recent advances in all areas of hydride chemistry research, including chemical reactivity, instrumental investigation, theory, and applications in the areas of catalysis, biochemistry and materials science. Many of the chapters have been written by the plenary lecturers of the EURO-Hydrides 2000 conference, but other leading scientists in this field have also been invited to contribute. The first part of the book focuses on the chemistry and catalysis of transition metal hydrides. Another block of chapters illustrates the most recent advances in the application of instrumental techniques to the study of the properties and reactivity of hydride compounds. The final part of the book illustrates the relevance of metal-hydrogen bonds in biochemistry and materials science. All of the chapters of this book have been evaluated by independent reviewers.
Author: Vladimir I. Bakhmutov Publisher: Wiley-Interscience ISBN: 9780470180969 Category : Science Languages : en Pages : 0
Book Description
This definitive reference consolidates current knowledge on dihydrogen bonding, emphasizing its role in organizing interactions in different chemical reactions and molecular aggregations. After an overview, it analyzes the differences between dihydrogen bonds, classical hydrogen bonds, and covalent bonds. It describes dihydrogen bonds as intermediates in intramolecular and intermolecular proton transfer reactions. It describes dihydrogen bonding in the solid-state, the gas phase, and in solution. This is the premier reference for physical chemists, biochemists, biophysicists, and chemical engineers.
Author: Shinichi Kawaguchi Publisher: Springer Science & Business Media ISBN: 3642501486 Category : Science Languages : en Pages : 129
Book Description
Metal complexes play important roles as catalysts or other participants in synthetic and biological reactions. Substrates and sometimes attacking reagents also are activated through coordination with metal atoms or ions. In these events the natures not only of the central metals but also of ancillary ligands exert important influences on the stability and reactivity of the coordinated substrates. A ligand in general can adopt various coordination modes depending on its chemical environment, thus functioning as a probe. The number of coordination modes increases with increasing complexity of the ligand. In this book it is shown that even the simplest mono- and diatomic ligands such as H, CO, and N2 exhibit a variety of coordination modes, which are related to their reactions. The thiocyanate anion is taken up as a representative of the triatomic ambidentate ligands, and factors influencing the preferences for N- und S-bonding are summarized. Coordination chemistry of ß-dicarbonyl compounds is a highlight of this book. Acetylacetone, one of the most familiar Werner ligands, is shown to favor -carbon and n-allylic bonding in many instances. Its versatile behaviour in changing coordination modes is revealed.
Author: Ying-Pin Chen Publisher: Springer ISBN: 3662535149 Category : Technology & Engineering Languages : en Pages : 363
Book Description
Volume 1 of a 4-volume series is a concise, authoritative and an eminently readable and enjoyable experience related to hydrogen production, storage and usage for portable and stationary power. Although the major focus is on hydrogen, discussion of fossil fuels and nuclear power is also presented where appropriate. This monograph is written by recognized experts in the field, and is both timely and appropriate as this decade will see application of hydrogen as an energy carrier, for example in transportation sector. The world's reliance on fossil fuels is due to the ever growing need for energy to sustain life and on-going progress; however exploitation also brings consequences such as emission of carbon, nitrogen and sulfur dioxides into the atmosphere. The collective influence of these photochemical gases is production of acid rain and an alternation of global temperatures, leading to record high temperatures in many parts of the world. The fossil fuel is unsustainable and thus there is a critical need for alternative sustainable energy resources. One universal energy carrier is hydrogen, which is the focus of this volume. This book is suitable for those who work in the energy field as technical experts, including engineers and scientists, as well as managers, policy and decision-makers, environmentalists and consultants. Students and practitioners such as lectures, teachers, legislators and their aids in the field of energy will find this book invaluable and a practical handbook or guide in the field of sustainable energy with emphasis on hydrogen as an energy carrier.
Author: Gregory J. Kubas
Author: Gregory J. Kubas
Author: Gregory J. Kubas
Author: Gregory J. Kubas
Author: Vladimir I. Bakhmutov
Author: Gregory J. Kubas
Author: Alain Dedieu
Author: Maurizio Peruzzini
Author: Vladimir I. Bakhmutov
Author: Shinichi Kawaguchi
Author: Ying-Pin Chen