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Author: C. Vidal Publisher: Springer Science & Business Media ISBN: 3642701965 Category : Science Languages : en Pages : 260
Book Description
Markedly apart from elementary particle physics, another current has been building up and cont i nuous ly growi ng within contemporary phys i cs for severa 1 decades, and even expanding into many other disciplines, especially chemistry, biology and, quite recently, economics. Several reasons account for this: presumably the most impor tant one lies in the fact that, whatever the specific problem, model or material concerned, the same basic mathematical features are always involved. In this way, a general phenomenology has emerged which, unlike thermodynamics, is no longer depen dent upon the details or specifics: what largely prevails is the nonlinear charac ter of the underlying dynamics. Perhaps we are witnessing the emergence of a "non linear physics"--In a way similar to the birth of "quantum physics" in the twen ties - a physics which deals with the general behaviour of systems, whatever they are or may be. Over the past fifteen years, chemical systems evolving sufficiently far from equilibrium have proved to be particularly well fitted to experimental research on nonlinear behaviour: oscillation, multistability, birhythmicity, chaotic evolution, spatial self-organization and hysteresis are displayed by chemical reactions whose number is growing each year. In this volume are collected the lectures, communica tions and posters (abstracts) presented at an international meeting entitled: "Non-Equilibrium Dynamics in Chemical Systems", held in Bordeaux (France), Septem ber 3 rd-lth, 1984.
Author: C. Vidal Publisher: Springer Science & Business Media ISBN: 3642701965 Category : Science Languages : en Pages : 260
Book Description
Markedly apart from elementary particle physics, another current has been building up and cont i nuous ly growi ng within contemporary phys i cs for severa 1 decades, and even expanding into many other disciplines, especially chemistry, biology and, quite recently, economics. Several reasons account for this: presumably the most impor tant one lies in the fact that, whatever the specific problem, model or material concerned, the same basic mathematical features are always involved. In this way, a general phenomenology has emerged which, unlike thermodynamics, is no longer depen dent upon the details or specifics: what largely prevails is the nonlinear charac ter of the underlying dynamics. Perhaps we are witnessing the emergence of a "non linear physics"--In a way similar to the birth of "quantum physics" in the twen ties - a physics which deals with the general behaviour of systems, whatever they are or may be. Over the past fifteen years, chemical systems evolving sufficiently far from equilibrium have proved to be particularly well fitted to experimental research on nonlinear behaviour: oscillation, multistability, birhythmicity, chaotic evolution, spatial self-organization and hysteresis are displayed by chemical reactions whose number is growing each year. In this volume are collected the lectures, communica tions and posters (abstracts) presented at an international meeting entitled: "Non-Equilibrium Dynamics in Chemical Systems", held in Bordeaux (France), Septem ber 3 rd-lth, 1984.
Author: R. P. Rastogi Publisher: Elsevier ISBN: 9780080551807 Category : Science Languages : en Pages : 356
Book Description
Introduction to Non-equilibrium Physical Chemistry presents a critical and comprehensive account of Non-equilibrium Physical Chemistry from theoretical and experimental angle. It covers a wide spectrum of non-equilibrium phenomena from steady state close to equilibrium to non-linear region involving transition to bistability, temporal oscillations, spatio-temporal oscillations and finally to far from equilibrium phenomena such as complex pattern formation, dynamic instability at interfaces, Chaos and complex growth phenomena (fractals) in Physico-chemical systems. Part I of the book deals with theory and experimental studies concerning transport phenomena in membranes (Thermo-osmosis,Electroosmotic ) and in continuous systems (Thermal diffusion,Soret effect) close to equilibrium Experimental tests provide insight into the domain of validity of Non-equilibrium Thermodynamics ,which is the major theoretical tool for this region. Later developments in Extended Irreversible Thermodynamics and Non-equilibrium Molecular dynamics have been discussed in the Appendix. Part II deals with non-linear steady states and bifurcation to multistability, temporal and spatio- temporal oscillations (Chemical waves). Similarly Part II deals with more complex phenomena such as Chaos and fractal growth occurring in very far from equilibrium region. Newer mathematical techniques for investigating such phenomena along with available experimental studies. Part IV deals with analogous non-equilibrium phenomena occurring in the real systems (Socio-political, Finance and Living systems etc.) for which physico-chemical systems discussed in earlier chapters provide a useful model for development of theories based on non-linear science and science of complexity. The book provides a critical account of theoretical studies on non-equilibrium phenomenon from region close to equilibrium to far equilibrium Experimental studies have been reported which provide test of the theories and their limitations Impacts of the concepts developed in non-equilibrium Physical Chemistry in sociology, economics and other social science and living systems has been discussed
Author: Yasar Demirel Publisher: Elsevier ISBN: 0444641130 Category : Science Languages : en Pages : 880
Book Description
Nonequilibrium Thermodynamics: Transport and Rate Processes in Physical, Chemical and Biological Systems, Fourth Edition emphasizes the unifying role of thermodynamics in analyzing natural phenomena. This updated edition expands on the third edition by focusing on the general balance equations for coupled processes of physical, chemical and biological systems. Updates include stochastic approaches, self-organization criticality, ecosystems, mesoscopic thermodynamics, constructual law, quantum thermodynamics, fluctuation theory, information theory, and modeling the coupled biochemical systems. The book also emphasizes nonequilibrium thermodynamics tools, such as fluctuation theories, mesoscopic thermodynamic analysis, information theories, and quantum thermodynamics in describing and designing small scale systems. Provides a useful text for seniors and graduate students from diverse engineering and science programs Highlights the fundamentals of equilibrium thermodynamics, transport processes and chemical reactions Expands the theory of nonequilibrium thermodynamics and its use in coupled transport processes and chemical reactions in physical, chemical and biological systems Presents a unified analysis for transport and rate processes in various time and space scales Discusses stochastic approaches in thermodynamic analysis, including fluctuation and information theories, mesoscopic nonequilibrium thermodynamics, constructal law and quantum thermodynamics
Author: Popielawski J Publisher: World Scientific ISBN: 9814569275 Category : Languages : en Pages : 440
Book Description
The proceedings discuss the theoretical methods used to describe a chemical system which is far from the equilibrium state, and this is illustrated by selected applications. Special attention is paid to very fast chemical reactions and systems in which external or internal noise is present. In particular, the following topics are covered:-the generalized Boltzmann/ Enskog equation for nonequilibrium systems,-stochastic methods for description of noise in chemical systems,-numerical simulations of systems far from equilibrium.
Author: Yasumasa Nishiura Publisher: American Mathematical Soc. ISBN: 9780821826256 Category : Mathematics Languages : en Pages : 340
Book Description
This book is devoted to the study of evolution of nonequilibrium systems. Such a system usually consists of regions with different dominant scales, which coexist in the space-time where the system lives. In the case of high nonuniformity in special direction, one can see patterns separated by clearly distinguishable boundaries or interfaces. The author considers several examples of nonequilibrium systems. One of the examples describes the invasion of the solid phase into the liquidphase during the crystallization process. Another example is the transition from oxidized to reduced states in certain chemical reactions. An easily understandable example of the transition in the temporal direction is a sound beat, and the author describes typical patterns associated with thisphenomenon. The main goal of the book is to present a mathematical approach to the study of highly nonuniform systems and to illustrate it with examples from physics and chemistry. The two main theories discussed are the theory of singular perturbations and the theory of dissipative systems. A set of carefully selected examples of physical and chemical systems nicely illustrates the general methods described in the book.
Author: National Research Council Publisher: National Academies Press ISBN: 0309063493 Category : Technology & Engineering Languages : en Pages : 325
Book Description
This book identifies opportunities, priorities, and challenges for the field of condensed-matter and materials physics. It highlights exciting recent scientific and technological developments and their societal impact and identifies outstanding questions for future research. Topics range from the science of modern technology to new materials and structures, novel quantum phenomena, nonequilibrium physics, soft condensed matter, and new experimental and computational tools. The book also addresses structural challenges for the field, including nurturing its intellectual vitality, maintaining a healthy mixture of large and small research facilities, improving the field's integration with other disciplines, and developing new ways for scientists in academia, government laboratories, and industry to work together. It will be of interest to scientists, educators, students, and policymakers.
Author: Gregoire Nicolis Publisher: Wiley-VCH ISBN: Category : Science Languages : en Pages : 520
Book Description
Membranes, Dissipative Structures, and Evolution Edited by G. Nicolis & R. Lefever Focuses on the problem of the emergence/maintenance of biological order at successively higher levels of complexity. Covers the spatiotemporal organization of simple biochemical networks; the formation of pluricellular or macromolecular assemblies; the evolution of these structures; and the functions of specific biological structures. Volume 29 in Advances in Chemical Physics Series, I. Prigogine & Stuart A. Rice, Editors. 1975 Theory and Applications of Molecular Paramagnetism Edited by E. A. Boudreaux & L. N. Mulay Comprehensively treats the basic theory of paramagnetic phenomena from both the classical and mechanical vantages. It examines the magnetic behavior of Lanthanide and Actinide elements as well as traditional transition metals. For each class of compounds, appropriate details of descriptive and mathematical theory are given before their applications. 1976 Theory and Aapplications of Molecular Diamagnetism Edited by L. N. Mulay & E. A. Boudreaux An invaluable reference for solving chemical problems in magnetics, magnetochemistry, and related areas where magnetic data are important, such as solid-state physics and optical spectroscopy. 1976
Author: Signe Kjelstrup Publisher: World Scientific ISBN: 9812779140 Category : Science Languages : en Pages : 451
Book Description
The purpose of this book is to encourage the use of non-equilibrium thermodynamics to describe transport in complex, heterogeneous media. With large coupling effects between the transport of heat, mass, charge and chemical reactions at surfaces, it is important to know how one should properly integrate across systems where different phases are in contact. No other book gives a prescription of how to set up flux equations for transports across heterogeneous systems. The authors apply the thermodynamic description in terms of excess densities, developed by Gibbs for equilibrium, to non-equilibrium systems. The treatment is restricted to transport into and through the surface. Using local equilibrium together with the balance equations for the surface, expressions for the excess entropy production of the surface and of the contact line are derived. Many examples are given to illustrate how the theory can be applied to coupled transport of mass, heat, charge and chemical reactions; in phase transitions, at electrode surfaces and in fuel cells. Molecular simulations and analytical studies are used to add insight. Sample Chapter(s). Chapter 1: Scope (169 KB). Contents: General Theory: The Entropy Production for a Homogeneous Phase: The Excess Entropy Production for the Surface; Flux Equations and Onsager Relations; Transport of Heat and Mass; Transport of Mass and Charge; Applications: Evaporation and Condensation; A Nonisothermal Concentration Cell; Adiabatic Electrode Reactions; The Formation Cell; Modeling the Polymer Electrolyte Fuel Cell; The Impedance of an Electrode Surface; The Non-Equilibrium Two-Phase van der Waals Model; and other chapters. Readership: Graduate students, researchers, lecturers and professionals in physics, nanoscience and surface science.
Author: C. Vidal
Author: C. Vidal
Author: 
Author: R. P. Rastogi
Author: Yasar Demirel
Author: Popielawski J
Author: J. Popielawski
Author: Yasumasa Nishiura
Author: National Research Council
Author: Gregoire Nicolis
Author: Signe Kjelstrup