Statistical Mechanics of Liquids and Solutions PDF Download

Author: Roland Kjellander
Publisher: CRC Press
ISBN: 1482244047
Category : Science
Languages : en
Pages : 424

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Book Description
The statistical mechanical theory of liquids and solutions is a fundamental area of physical sciences with important implications for many industrial applications. This book shows how you can start from basic laws for the interactions and motions of microscopic particles and calculate how macroscopic systems of these particles behave, thereby explaining properties of matter at the scale that we perceive. Using this microscopic, molecular approach, the text emphasizes clarity of physical explanations for phenomena and mechanisms relevant to fluids, addressing the structure and behavior of liquids and solutions under various conditions. A notable feature is the author’s treatment of forces between particles that include nanoparticles, macroparticles, and surfaces. The book also provides an expanded, in-depth treatment of polar liquids and electrolytes.

Author: Jean-Louis Bretonnet
Publisher: Cambridge Scholars Publishing
ISBN: 152755970X
Category : Science
Languages : en
Pages : 582

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Book Description
In a simple and accessible form, this book presents a unified approach to the physics of the liquid state, both in and out of equilibrium. It discerns, behind the seemingly anarchistic proliferation of phenomena observable in the liquid state, the sequence of causes and effects and, where appropriate, the underlying rules that preside over the general principles. The book begins by introducing the fundamental concepts of statistical mechanics, such as classical and quantum mechanics, probability theory, and the kinetic theory of gases, before moving on to discuss theoretical methods in order to contextualise the study of liquids. The last final section is devoted to ordering in complex fluids. It includes detailed technical notes and explicit calculations, and will appeal to graduate students in physics and chemistry. It will also be of interest the reader interested in statistical mechanics and their application to the physics of dense matter. This book will certainly become an indispensable reference for students and researchers who wish to become familiar with a multifaceted process looking towards new horizons.

Author: Jean-Pierre Hansen
Publisher: Elsevier
ISBN: 0080571018
Category : Science
Languages : en
Pages : 556

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Book Description
This book gives a comprehensive and up-to-date treatment of the theory of "simple" liquids. The new second edition has been rearranged and considerably expanded to give a balanced account both of basic theory and of the advances of the past decade. It presents the main ideas of modern liquid state theory in a way that is both pedagogical and self-contained. The book should be accessible to graduate students and research workers, both experimentalists and theorists, who have a good background in elementary mechanics. Compares theoretical deductions with experimental results Molecular dynamics Monte Carlo computations Covers ionic, metallic, and molecular liquids

Author: Biman Bagchi
Publisher: CRC Press
ISBN: 0429833601
Category : Science
Languages : en
Pages : 513

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Book Description
This book covers the broad subject of equilibrium statistical mechanics along with many advanced and modern topics such as nucleation, spinodal decomposition, inherent structures of liquids and liquid crystals. Unlike other books on the market, this comprehensive text not only deals with the primary fundamental ideas of statistical mechanics but also covers contemporary topics in this broad and rapidly developing area of chemistry and materials science.

Author: W. Ronald Fawcett
Publisher: Oxford University Press
ISBN: 9780198025443
Category : Science
Languages : en
Pages : 638

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Book Description
Fifty years ago solution chemistry occupied a major fraction of physical chemistry textbooks, and dealt mainly with classical thermodynamics, phase equilibria, and non-equilibrium phenomena, especially those related to electrochemistry. Much has happened in the intervening period, with tremendous advances in theory and the development of important new experimental techniques. This book brings the reader through the developments from classical macroscopic descriptions to more modern microscopic details.

Author: Jean-Pierre Hansen
Publisher: Academic Press
ISBN: 012387033X
Category : Science
Languages : en
Pages : 636

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Book Description
Comprehensive coverage of topics in the theory of classical liquids Widely regarded as the standard text in its field, Theory of Simple Liquids gives an advanced but self-contained account of liquid state theory within the unifying framework provided by classical statistical mechanics. The structure of this revised and updated Fourth Edition is similar to that of the previous one but there are significant shifts in emphasis and much new material has been added. Major changes and Key Features in content include: Expansion of existing sections on simulation methods, liquid-vapour coexistence, the hierarchical reference theory of criticality, and the dynamics of super-cooled liquids. New sections on binary fluid mixtures, surface tension, wetting, the asymptotic decay of pair correlations, fluids in porous media, the thermodynamics of glasses, and fluid flow at solid surfaces. An entirely new chapter on applications to 'soft matter' of a combination of liquid state theory and coarse graining strategies, with sections on polymer solutions and polymer melts, colloidal dispersions, colloid-polymer mixtures, lyotropic liquid crystals, colloidal dynamics, and on clustering and gelation. Expansion of existing sections on simulation methods, liquid-vapour coexistence, the hierarchian reference of criticality, and the dynamics of super-cooled liquids. New sections on binary fluid mixtures, surface tension, wetting, the asymptotic decay of pair correlations, fluids in porous media, the thermodynamics of glasses, and fluid flow at solid surfaces. An entirely new chapter on applications to 'soft matter' of a combination of liquid state theory and coarse graining strategies, with sections on polymer solutions and polymer melts, colloidal dispersions, colloid-polymer mixtures, lyotropic liquid crystals, colloidal dynamics, and on clustering and gelation.

Author: Denis J. Evans
Publisher: ANU E Press
ISBN: 1921313234
Category : Science
Languages : en
Pages : 318

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Book Description
"There is a symbiotic relationship between theoretical nonequilibrium statistical mechanics on the one hand and the theory and practice of computer simulation on the other. Sometimes, the initiative for progress has been with the pragmatic requirements of computer simulation and at other times, the initiative has been with the fundamental theory of nonequilibrium processes. This book summarises progress in this field up to 1990"--Publisher's description.

Author: Fumio Hirata
Publisher: CRC Press
ISBN: 9781032174549
Category :
Languages : en
Pages : 300

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Book Description
This book provides theoretical foundation for processes such as molecular recognition, which play essential roles in life phenomena. A key word to understand such processes is "water, which playsan essential role in life phenomena both in equilibrium and non-equilibrium processes. The book starts from explaining the RISM and 3D-RISM theories, the

Author: Duane C Wallace
Publisher: World Scientific
ISBN: 9814487805
Category : Science
Languages : en
Pages : 328

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Book Description
This important book presents a unified formulation from first principles of the Hamiltonian and statistical mechanics of metallic and insulating crystals, amorphous solids, and liquids. Extensive comparison of theory and experiment provides an accurate understanding of the statistical properties of phonons, electrons, and phonon–phonon and electron–phonon interactions in elemental crystals and liquids. Questions are posed along the following lines: What is the “best” theory for a given property? How accurate is a good theory? What information is gained by a comparison of theory and experiment? How accurate is a good experiment? Contents:Condensed Matter HamiltonianStatistical MechanicsLattice DynamicsStatistical Mechanics of CrystalsLiquid Dynamics and Statistical MechanicsPhase Transitions and Nonequilibrium Processes Readership: Researchers, academics and graduate students in condensed matter physics. Keywords:Condensed Matter Hamiltonian;Statistical Mechanics;Lattice Dynamics;Crystals;Liquid Dynamics;Phase Transitions;Metastable StatesReviews:“This is a valuable and clearly written book in an important area of condensed matter theory. There is extensive contact between theoretical predictions and experiments. For both students and young research workers there are useful collections of problems which lead to further insight into the area covered. Quantitative equations of state are given prominence.”Norman H March Oxford University “This is an authoritative account of the physics and thermodynamics behind an understanding of the equation of state. It concentrates on elements and the use of pseudopotential perturbation theory for the simple metals provides insight and a basis for computer simulations. The account combines careful theoretical analyses, and Local-Density-Theory results, with interpretation of the best experimental data available and may be unique in incorporating the liquid, as well as the crystalline state. The very complete set of problems included would make it very appropriate as the text for a general course on the equation of state.”Walt Harrison Stanford University “Whatever the author does, he does it first class. His book is something we use to gauge excellence in the field, and I have no doubt that this one will be no exception. But this book is different from other books he wrote. It is more personal in that he has not hesitated to express his personal views strongly, but in a scholarly fashion.”Y Horie Los Alamos National Laboratory “This is a book of condensed matter physics that gives equal emphasis to solids and liquids. The author focuses on the equation of state of the simple elements and reviews the methods for passing from the Hamiltonian through statistical mechanics to the equation of state of the solid and liquid and the computation of the melting curve. For the reader who wants an introduction to the capability of modern statistical physics for accurate prediction of thermodynamic functions, this is the book.”David Young Lawrence Livermore National Laboratory “This book, in my mind, represents an extremely powerful resource to any researcher working in condensed matter physics and especially equation of state theory. It is clear from 'Statistical Physics of Crystals and Liquids' that Dr Wallace has a special gift of taking complex physics concepts and explaining them with the greatest of clarity. His ability clearly distinguishes this book from those written by more novice authors … In summary, I believe this book should be highly marketed as I expect that there is a large condensed matter community that would benefit from reading it.”Brad Clements Los Alamos National Laboratory “The three investigated subjects, only fragments of which are covered in other textbooks and research treatises, make this book a very useful one for specialists in statistical mechanics and structure of matter.”Zentralblatt MATH “… the book comprises a brisk overview of solids that reaches timely topics of nonequilibrium processes … its structure lends itself well to being used as an instructional text in either an advanced undergraduate course or a graduate treatment of the subject … The review of statistical mechanics is straightforward to anyone with prior exposure to the subject, and is nearly complete … Wallace has done an excellent job of achieving the goals set out in the introduction of the book in a format that is clean and easy to read with a notation that is not confusing.”MRS Bulletin “This book covers ‘equation of state’ but also atomic dynamics. In these fields it offers a useful summary of methods and results, which prove how successful modern computational methods have become.”Contemporary Physics

Author: Walter Schirmacher
Publisher: Springer
ISBN: 3319069500
Category : Science
Languages : en
Pages : 167

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Book Description
This set of lectures provides an introduction to the structure, thermodynamics and dynamics of liquids, binary solutions and polymers at a level that will enable graduate students and non-specialist researchers to understand more specialized literature and to possibly start their own work in this field. Part I starts with the introduction of distribution functions, which describe the statistical arrangements of atoms or molecules in a simple liquid. The main concepts involve mean field theories like the Perkus-Yevick theory and the random phase approximation, which relate the forces to the distribution functions. In order to provide a concise, self-contained text, an understanding of the general statistical mechanics of an interacting many-body system is assumed. The fact that in a classic liquid the static and dynamic aspects of such a system can be discussed separately forms the basis of the two-fold structure of this approach. In order to allow polymer melts and solutions to be discussed, a short chapter acquaints readers with scaling concepts by discussing random walks and fractals. Part II of the lecture series is essentially devoted to the presentation of the dynamics of simple and complex liquids in terms of the generalized hydrodynamics concept, such as that introduced by Mori and Zwanzig. A special topic is a comprehensive introduction of the liquid-glass transition and its discussion in terms of a mode-coupling theory.