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Hypercarbon Chemistry

Hypercarbon Chemistry PDF Author: George A. Olah
Publisher: John Wiley & Sons
ISBN: 9781118016459
Category : Science
Languages : en
Pages : 480

Book Description
The essential new edition of the book that put hypercarbon chemistry on the map A comprehensive and contemporary treatment of the chemistry of hydrocarbons (alkanes, alkenes, alkynes, and aromatics) towards electrophiles, Hypercarbon Chemistry, Second Edition deals with all major aspects of such chemistry involved in hydrocarbon transformations, and of the structural and reaction chemistry of carboranes, mixed hydrides in which both carbon and boron atoms participate in the polyhedral molecular frameworks. Despite the firmly established tetravalency, carbon can bond simultaneously to five or more other atoms. "Hypercarbon" bonding permeates much organic, inorganic and organometallic chemistry, and the book serves as the compendium for this phenomenon. Copious diagrams illustrate the rich variety of hypercarbon structures now known, and patterns therein. Individual chapters deal with specific categories of compound (e.g. organometallics, carboranes, carbocations) or transformations that proceed through transient hypercarbon species, detailing fundamental chemistry, including reactivity, selectivity, stereochemistry, mechanistic factors and more.

Hypercarbon Chemistry

Hypercarbon Chemistry PDF Author: George A. Olah
Publisher: John Wiley & Sons
ISBN: 9781118016459
Category : Science
Languages : en
Pages : 480

Book Description
The essential new edition of the book that put hypercarbon chemistry on the map A comprehensive and contemporary treatment of the chemistry of hydrocarbons (alkanes, alkenes, alkynes, and aromatics) towards electrophiles, Hypercarbon Chemistry, Second Edition deals with all major aspects of such chemistry involved in hydrocarbon transformations, and of the structural and reaction chemistry of carboranes, mixed hydrides in which both carbon and boron atoms participate in the polyhedral molecular frameworks. Despite the firmly established tetravalency, carbon can bond simultaneously to five or more other atoms. "Hypercarbon" bonding permeates much organic, inorganic and organometallic chemistry, and the book serves as the compendium for this phenomenon. Copious diagrams illustrate the rich variety of hypercarbon structures now known, and patterns therein. Individual chapters deal with specific categories of compound (e.g. organometallics, carboranes, carbocations) or transformations that proceed through transient hypercarbon species, detailing fundamental chemistry, including reactivity, selectivity, stereochemistry, mechanistic factors and more.

Hypercarbon Chemistry

Hypercarbon Chemistry PDF Author: George A. Olah
Publisher: Wiley-Interscience
ISBN:
Category : Science
Languages : en
Pages : 346

Book Description
This pioneering text is the first to point out the emerging significance of higher-valent carbon compounds. Describes the compounds of carbon with coordination numbers greater than four. Explores the delocalized bonds of pi[l.c. Greek letter] aromatic molecules as a basis for rational description of orbitals; localized multicentered orbitals; the interactions of metallic ions with other atoms and molecules; the skeletal electron counts as a guide for synthesis; and the isolobal concept. Illustrates the way in which these subjects bring together structure and reactivity in the great diversity of novel carbon chemistry and its relationship to that of boron, lithium, hydrogen, the metals, and others.

A Life of Magic Chemistry

A Life of Magic Chemistry PDF Author: George A. Olah
Publisher: John Wiley & Sons
ISBN: 1118839900
Category : Science
Languages : en
Pages : 336

Book Description
The autobiography of a Nobel Prize winner, this book tells us about George Olah's fascinating research into extremely strong superacids and how it yielded the common term "magic acids." Olah guides us through his long and remarkable journey, from Budapest to Cleveland to Los Angeles, with a stopover in Stockholm. This updated autobiography of a Nobel Prize winner George A. Olah: Chronicles the distinguished career of a chemist whose work in a broad range of chemistry areas, and most notably that in methane chemistry, led to technologies that impact the processing and utility of alternative fuels Is based on Olah's work on extremely strong superacids and how they yielded the common term, "magic acids" Details events since the publication of the first edition in 2000 Inspires readers with details on Dr. Olah's successful recent research on methanol, intended to help provide a solution to "the oil problem"

Chemistry, 1991-1995

Chemistry, 1991-1995 PDF Author: Bo G. Malmstr”m
Publisher: World Scientific
ISBN: 9789810226800
Category : Science
Languages : en
Pages : 312

Book Description
A collection of the Nobel Lectures delivered by the prizewinners in chemistry, together with their biographies, portraits and the presentation speeches.

Hydrocarbon Chemistry, 2 Volume Set

Hydrocarbon Chemistry, 2 Volume Set PDF Author: George A. Olah
Publisher: John Wiley & Sons
ISBN: 1119390532
Category : Science
Languages : en
Pages : 1216

Book Description
This book provides an unparalleled contemporary assessment of hydrocarbon chemistry – presenting basic concepts, current research, and future applications. • Comprehensive and updated review and discussion of the field of hydrocarbon chemistry • Includes literature coverage since the publication of the previous edition • Expands or adds coverage of: carboxylation, sustainable hydrocarbons, extraterrestrial hydrocarbons • Addresses a topic of special relevance in contemporary science, since hydrocarbons play a role as a possible replacement for coal, petroleum oil, and natural gas as well as their environmentally safe use • Reviews of prior edition: “...literature coverage is comprehensive and ideal for quickly reviewing specific topics...of most value to industrial chemists...” (Angewandte Chemie) and “...useful for chemical engineers as well as engineers in the chemical and petrochemical industries.” (Petroleum Science and Technology)

Perspectives on Structure and Mechanism in Organic Chemistry

Perspectives on Structure and Mechanism in Organic Chemistry PDF Author: Felix A. Carroll
Publisher: John Wiley & Sons
ISBN: 1119808618
Category : Science
Languages : en
Pages : 869

Book Description
PERSPECTIVES ON STRUCTURE AND MECHANISM IN ORGANIC CHEMISTRY “Beyond the basics” physical organic chemistry textbook, written for advanced undergraduates and beginning graduate students Based on the author’s first-hand classroom experience, Perspectives on Structure and Mechanism in Organic Chemistry uses complementary conceptual models to give new perspectives on the structures and reactions of organic compounds, with the overarching goal of helping students think beyond the simple models of introductory organic chemistry courses. Through this approach, the text better prepares readers to develop new ideas in the future. In the 3rd Edition, the author thoroughly updates the topics covered and reorders the contents to introduce computational chemistry earlier and to provide a more natural flow of topics, proceeding from substitution, to elimination, to addition. About 20% of the 438 problems have been either replaced or updated, with answers available in the companion solutions manual. To remind students of the human aspect of science, the text uses the names of investigators throughout the text and references material to original (or accessible secondary or tertiary) literature as a guide for students interested in further reading. Sample topics covered in Perspectives on Structure and Mechanism in Organic Chemistry include: Fundamental concepts of organic chemistry, covering atoms and molecules, heats of formation and reaction, bonding models, and double bonds Density functional theory, quantum theory of atoms in molecules, Marcus Theory, and molecular simulations Asymmetric induction in nucleophilic additions to carbonyl compounds and dynamic effects on reaction pathways Reactive intermediates, covering reaction coordinate diagrams, radicals, carbenes, carbocations, and carbanions Methods of studying organic reactions, including applications of kinetics in studying reaction mechanisms and Arrhenius theory and transition state theory A comprehensive yet accessible reference on the subject, Perspectives on Structure and Mechanism in Organic Chemistry is an excellent learning resource for students of organic chemistry, medicine, and biochemistry. The text is ideal as a primary text for courses entitled Advanced Organic Chemistry at the upper undergraduate and graduate levels.

Across Conventional Lines

Across Conventional Lines PDF Author: George A Olah
Publisher: World Scientific
ISBN: 9814498548
Category : Science
Languages : en
Pages : 1504

Book Description
In the course of his distinguished career spanning about half a century, George A Olah, winner of the 1994 Nobel Prize for Chemistry, has been exceedingly prolific and has published more than 1000 scientific papers and 15 books and holds more than 100 patents. This invaluable volume contains about 250 papers selected for their breadth and current importance. Contents: Volume 1: Early StudiesElectrophilic Aromatic SubstitutionFriedel-Crafts ChemistryStable (Persistent), Long Lived Carbocations: General AspectsTrivalent Alkyl (Cycloalkyl) Cations (Carbenium Ions)π- and πσ-Delocalized CarbocationsHeteroatom and Metal Substituted CarbocationsCarbodicationsAromatic and Homoaromatic Cations and DicationsFive and Higher Coordinate (Nonclassical) Carbonium Ions: Controversy and SignificanceMagic Acid and Superacid ChemistrySolid Superacid CatalysisFrom Kekulé's Four-Valent Carbon to Higher Coordinate HypercarbonElectrophilic Chemistry of Saturated HydrocarbonsOnium Ions: General Aspects Volume 2: Oxonium, Sulfonium, Selenonium and Telluronium IonsAzonium IonsHalonium IonsMiscellaneous Onium IonsGitonic Onium Di(Poly)cations and Superelectrophilic ActivationSynthetic Reagents, Methods and ReactionsOxygenation and SulfurationNitration and Nitrosation ChemistryOrganofluorine ChemistryOrganometallic ChemistryPolymer ChemistryNew Approaches to Future of Hydrocarbon NeedsMiscellaneous Studies keywords:

Perspectives on Structure and Mechanism in Organic Chemistry, Solution Manual

Perspectives on Structure and Mechanism in Organic Chemistry, Solution Manual PDF Author: Felix A. Carroll
Publisher: John Wiley & Sons
ISBN: 1119808650
Category : Science
Languages : en
Pages : 166

Book Description
SOLUTIONS MANUAL FOR PERSPECTIVES ON STRUCTURE AND MECHANISM IN ORGANIC CHEMISTRY Based on the author’s first-hand classroom experience, this solutions manual complements the 3rd edition of Perspectives on Structure and Mechanism in Organic Chemistry. The solutions to the 438 textbook problems help students increase their understanding of physical organic chemistry, and more than 550 references stimulate their engagement with the chemical literature.

Candid Science: Conversations With Famous Chemists

Candid Science: Conversations With Famous Chemists PDF Author: Istvan Hargittai
Publisher: World Scientific
ISBN: 1783262141
Category : Science
Languages : en
Pages : 530

Book Description
In this book, 36 famous chemists, including 18 Nobel laureates, tell about their lives in science, the beginnings of their careers, their aspirations, and their hardships and triumphs. The reader will learn about their seminal discoveries, and the conversations in the book bring out the humanity of these great scientists. NMR spectroscopy, computational chemistry, the drama of buckminsterfullerene, the story of the Pill, the politics of atmospheric chemistry and the resonance theory, the beginnings of molecular mechanics and modern stereochemistry are examples of the topics discussed first-hand by, in all likelihood, the most appropriate persons.

Petroleum Refining

Petroleum Refining PDF Author: Mark J. Kaiser
Publisher: CRC Press
ISBN: 1466563028
Category : Science
Languages : en
Pages : 725

Book Description
For four decades, Petroleum Refining has guided thousands of readers toward a reliable understanding of the field, and through the years has become the standard text in many schools and universities around the world offering petroleum refining classes, for self-study, training, and as a reference for industry professionals. The sixth edition of this perennial bestseller continues in the tradition set by Jim Gary as the most modern and authoritative guide in the field. Updated and expanded to reflect new technologies, methods, and topics, the book includes new discussion on the business and economics of refining, cost estimation and complexity, crude origins and properties, fuel specifications, and updates on technology, process units, and catalysts. The first half of the book is written for a general audience to introduce the primary economic and market characteristics of the industry and to describe the inputs and outputs of refining. Most of this material is new to this edition and can be read independently or in parallel with the rest of the text. In the second half of the book, a technical review of the main process units of a refinery is provided, beginning with distillation and covering each of the primary conversion and treatment processes. Much of this material was reorganized, updated, and rewritten with greater emphasis on reaction chemistry and the role of catalysis in applications. Petroleum Refining: Technology, Economics, and Markets is a book written for users, the practitioners of refining, and all those who want to learn more about the field.