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Author: R.C. Larock Publisher: Springer Science & Business Media ISBN: 3642700047 Category : Science Languages : en Pages : 432
Book Description
The field of organometallic chemistry has enjoyed explosive growth in recent years. During this time a rapidly increasing number of metals have found utility in organic synthesis as the corresponding organometallic compounds. The sub ject of "Organic Synthesis by Means of Transition Metal Complexes" was reviewed in the first volume of this series of monographs. This volume deals primarily with the appli cation of organomercury compounds in organic synthesis (exclusive of solvomercuration-demercuration reactions), but will of necessity involve a number of reactions of other organometallics as well. Organomercurials are among the oldest known organo metallics and were perhaps the first to have an entire book devoted to their chemistry, when Whitmore wrote an American Chemical Society monograph on the subject in 1921. Subsequently, two very detailed monographs on the subject have appeared. In 1967 "The Organic Compounds of Mercury", volume 4 in the series "Methods of Elemento Organic Chemistry" appeared and this was followed in 1974 by Houben Weyl's full volume, Band XIII/2b, devoted entirely to the organometallic compounds of mercury. These books cover the entire field of organomercury chemistry.
Author: R.C. Larock Publisher: Springer Science & Business Media ISBN: 3642700047 Category : Science Languages : en Pages : 432
Book Description
The field of organometallic chemistry has enjoyed explosive growth in recent years. During this time a rapidly increasing number of metals have found utility in organic synthesis as the corresponding organometallic compounds. The sub ject of "Organic Synthesis by Means of Transition Metal Complexes" was reviewed in the first volume of this series of monographs. This volume deals primarily with the appli cation of organomercury compounds in organic synthesis (exclusive of solvomercuration-demercuration reactions), but will of necessity involve a number of reactions of other organometallics as well. Organomercurials are among the oldest known organo metallics and were perhaps the first to have an entire book devoted to their chemistry, when Whitmore wrote an American Chemical Society monograph on the subject in 1921. Subsequently, two very detailed monographs on the subject have appeared. In 1967 "The Organic Compounds of Mercury", volume 4 in the series "Methods of Elemento Organic Chemistry" appeared and this was followed in 1974 by Houben Weyl's full volume, Band XIII/2b, devoted entirely to the organometallic compounds of mercury. These books cover the entire field of organomercury chemistry.
Author: A. N. Nesmeyanov Publisher: Elsevier ISBN: 1483151360 Category : Science Languages : en Pages : 1189
Book Description
Selected Works in Organic Chemistry focuses on the processes, methodologies, reactions, and approaches involved in organic chemistry, including analysis of diazo compounds and infrared absorption spectra. The publication first offers information on the method of synthesis of aromatic organomercury salts; method of synthesis of symmetrical aromatic organomercury compounds; and diazo method of synthesis of aromatic organomercury compounds with negative substituent in nucleus. The reaction of aliphatic diazo compounds with mercury salts and synthesis of organotin compounds through diazo compounds are also discussed. The manuscript takes a look at the synthesis of aromatic organometal compounds of bismuth through diazo compounds; synthesis of aromatic germanium compounds through aryldiazonium tetrafluoroborate; and reduction of organomercury compounds by bivalent tin salts as a method of synthesis. The text also examines the activation energy of the disaggregation process of associated alkoxy titanium derivatives and determination of positions of substituents in ferrocene compounds by means of infrared absorption spectra. The publication is a valuable reference for readers interested in organic chemistry.
Author: Manfred Schlosser Publisher: John Wiley & Sons ISBN: 1118484754 Category : Science Languages : en Pages : 1008
Book Description
WINNER of the 2013 PROSE Award in Chemistry & Physics This latest edition enables readers to master new classes of organometallic compounds and syntheses A popular resource used by synthetic organic chemists around the world, this book enables readers to conduct seamless synthetic reactions involving key organometallics. Each reaction is set forth in the book's acclaimed recipe-style format so that readers can easily replicate the results in their own labs. Moreover, each chapter has been written by a world leader in the field of organometallics in organic synthesis. These authors offer hands-on guidance and practical examples illustrating the preparation of organometallics and its application in organic synthesis. This Third Manual of Organometallics in Synthesis features completely new content and topics, with an eye towards providing researchers with the most useful and practical reference on the synthesis of organometallics. Organized into chapters by type of organometallic compound, the book covers: Organoalkali chemistry Organomagnesium and organozinc chemistry Organosilicon and relating organotin chemistry Organoiron chemistry Organopalladium chemistry Within each chapter, readers will find background information to learn more about the class of organometallics as well as mechanistic considerations. The authors thoroughly discuss the various methods of preparing the organometallic compounds presented in the book and outline their uses in synthetic reactions. In addition to current applications, the authors explore future research opportunities for each organometallic class. References at the end of each chapter enable readers to explore all the topics in greater depth. More and more industrial processes rely on organometallic chemistry. As a result, readers will find this book's step-by-step instructions essential in such fields as natural product synthesis, pharmaceuticals, fine chemicals, biotechnology, polymers, and materials science.
Author: Publisher: Georg Thieme Verlag ISBN: 3131806648 Category : Science Languages : de Pages : 462
Book Description
Houben-Weyl is the acclaimed reference series for preparative methods in organic chemistry, in which all methods are organized accor ding to the class of compound or functional group to be synthesized. The Houben-Weyl volumes contain 146 000 product-specific experi mental procedures, 580 000 structures, and 700 000 references. The preparative significance of the methods for all classes of compou nds is critically evaluated. The series includes data from as far back as the early 1800s to 2003. // The content of this e-book was originally published in 1974.
Author: R.C. Larock Publisher: Springer ISBN: 9783642882067 Category : Science Languages : en Pages : 607
Book Description
The widespread utilization of organometallic reagents in organic synthesis has been one of the major developments in organic chemistry in recent years. The earlier Springer monograph entitled "Organic Synthesis by Means of Trans i tion Metal Complexes" covered many of the more recent advances in this area. The present volume covers applica tions of the very valuable solvomercuration-demercuration sequence in organic synthesis. Organomercurials have played an important role in organic chemistry for over a century. They have been known since 1852 and major monographs covering their chemistry have appeared in 1921 ("Organic Compounds of Mercury" by F. C. Whitmore), 1967 ("The Organic Compounds of Mercury", volume 4 in the series "Methods of Elemento Organic Chemistry", edited by L. G. Makarova and A. N. Nesmeyanov) and 1974 ("Metallorganische Verbindungen Hg", Houben-Weyl: Methoden der Organischen Chemie, 4th ed., Vol. 13/2b, edited by H. Staub, K. P. Zeller and H. Leditsche). My own personal interest in the application of organo mercurials in organic synthesis goes back to the late 1960's when I first became involved in the development of new synthetic routes to organomercurials. In 1976 I wrote a chapter entitled "Organomercurials as Reagents and Inter mediates in Organic Synthesis" for a book entitled "New Applications of Organometallic Reagents in Organic Syn thesis". That chapter was subsequently pared down to a brief review article in Angewandte Chemie which appeared in 1978 and a further article in Tetrahedron Reports in 1982.
Author: A. McKillop Publisher: Elsevier ISBN: 9780080423180 Category : Science Languages : en Pages : 698
Book Description
The individual chapters in this volume cover the scope and impact of main group organometallic compounds and reagents on organic synthesis during the last ten to fifteen years. In a number of chapters, topics are dealt with in detail that either were not covered at all in COMC (eg selenium, tellurium) or were given scant attention (eg oxymercuration, organoantimony compounds). Certain topics, like directed metallation and LiKOR bases have only achieved prominence in synthesis in the last ten years, and are now reviewed by leading experts.
Author: Manfred Schlosser Publisher: ISBN: Category : Science Languages : en Pages : 622
Book Description
This book presents a practical introduction into the organic syntheses using organometallic reagents and catalysts. Addressing the most important issues, it restricts itself to the derivatives of less than a dozen metals, focusing on those which are most versatile and frequently used. Provides practical advice on how to choose the best methods and conditions and how to carry out and work up organometallic reactions. Details the fundamental facts and the mechanistic background needed to fully understand why a reaction follows a given course.
Author: R.C. Larock
Author: R.C. Larock
Author: Richard C. Larock
Author: A. N. Nesmeyanov
Author: Manfred Schlosser
Author: 
Author: R.C. Larock
Author: Charles Andrew McAuliffe
Author: Frank Clifford Whitmore
Author: A. McKillop
Author: Manfred Schlosser