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Thermodynamics and Fluctuations far from Equilibrium

Thermodynamics and Fluctuations far from Equilibrium PDF Author: John Ross
Publisher: Springer Science & Business Media
ISBN: 3540745556
Category : Science
Languages : en
Pages : 207

Book Description
This book deals with the formulation of the thermodynamics of chemical and other systems far from equilibrium. It contains applications to non-equilibrium stationary states and approaches to such states, systems with multiple stationary states, stability and equi-stability conditions, reaction diffusion systems, transport properties, and electrochemical systems. The theoretical treatment is complemented by experimental results to substantiate the formulation.

Thermodynamics and Fluctuations far from Equilibrium

Thermodynamics and Fluctuations far from Equilibrium PDF Author: John Ross
Publisher: Springer Science & Business Media
ISBN: 3540745556
Category : Science
Languages : en
Pages : 207

Book Description
This book deals with the formulation of the thermodynamics of chemical and other systems far from equilibrium. It contains applications to non-equilibrium stationary states and approaches to such states, systems with multiple stationary states, stability and equi-stability conditions, reaction diffusion systems, transport properties, and electrochemical systems. The theoretical treatment is complemented by experimental results to substantiate the formulation.

Non-Equilibrium Thermodynamics

Non-Equilibrium Thermodynamics PDF Author: S. R. De Groot
Publisher: Courier Corporation
ISBN: 0486153509
Category : Science
Languages : en
Pages : 532

Book Description
Classic monograph treats irreversible processes and phenomena of thermodynamics: non-equilibrium thermodynamics. Covers statistical foundations and applications with chapters on fluctuation theory, theory of stochastic processes, kinetic theory of gases, more.

Statistical Thermodynamics of Nonequilibrium Processes

Statistical Thermodynamics of Nonequilibrium Processes PDF Author: Joel Keizer
Publisher: Springer Science & Business Media
ISBN: 1461210542
Category : Science
Languages : en
Pages : 517

Book Description
The structure of the theory ofthermodynamics has changed enormously since its inception in the middle of the nineteenth century. Shortly after Thomson and Clausius enunciated their versions of the Second Law, Clausius, Maxwell, and Boltzmann began actively pursuing the molecular basis of thermo dynamics, work that culminated in the Boltzmann equation and the theory of transport processes in dilute gases. Much later, Onsager undertook the elucidation of the symmetry oftransport coefficients and, thereby, established himself as the father of the theory of nonequilibrium thermodynamics. Com bining the statistical ideas of Gibbs and Langevin with the phenomenological transport equations, Onsager and others went on to develop a consistent statistical theory of irreversible processes. The power of that theory is in its ability to relate measurable quantities, such as transport coefficients and thermodynamic derivatives, to the results of experimental measurements. As powerful as that theory is, it is linear and limited in validity to a neighborhood of equilibrium. In recent years it has been possible to extend the statistical theory of nonequilibrium processes to include nonlinear effects. The modern theory, as expounded in this book, is applicable to a wide variety of systems both close to and far from equilibrium. The theory is based on the notion of elementary molecular processes, which manifest themselves as random changes in the extensive variables characterizing a system. The theory has a hierarchical character and, thus, can be applied at various levels of molecular detail.

Understanding Non-equilibrium Thermodynamics

Understanding Non-equilibrium Thermodynamics PDF Author: Georgy Lebon
Publisher: Springer Science & Business Media
ISBN: 3540742522
Category : Science
Languages : en
Pages : 326

Book Description
Discover the many facets of non-equilibrium thermodynamics. The first part of this book describes the current thermodynamic formalism recognized as the classical theory. The second part focuses on different approaches. Throughout the presentation, the emphasis is on problem-solving applications. To help build your understanding, some problems have been analyzed using several formalisms to underscore their differences and their similarities.

Beyond Equilibrium Thermodynamics

Beyond Equilibrium Thermodynamics PDF Author: Hans Christian Öttinger
Publisher: John Wiley & Sons
ISBN: 0471727911
Category : Technology & Engineering
Languages : en
Pages : 651

Book Description
Beyond Equilibrium Thermodynamics fills a niche in the market by providing a comprehensive introduction to a new, emerging topic in the field. The importance of non-equilibrium thermodynamics is addressed in order to fully understand how a system works, whether it is in a biological system like the brain or a system that develops plastic. In order to fully grasp the subject, the book clearly explains the physical concepts and mathematics involved, as well as presenting problems and solutions; over 200 exercises and answers are included. Engineers, scientists, and applied mathematicians can all use the book to address their problems in modelling, calculating, and understanding dynamic responses of materials.

Non-equilibrium Thermodynamics

Non-equilibrium Thermodynamics PDF Author: Sybren Ruurds Groot
Publisher:
ISBN:
Category : Irreversible processes
Languages : en
Pages : 532

Book Description


Fluctuations and Sensitivity in Nonequilibrium Systems

Fluctuations and Sensitivity in Nonequilibrium Systems PDF Author: W. Horsthemke
Publisher: Springer Science & Business Media
ISBN: 3642465080
Category : Science
Languages : en
Pages : 281

Book Description
This volume contains the invited lectures and a selection of the contributed papers and posters of the workshop on "Fluctuations and Sensitivity in Nonequil ibrium Systems", held at the Joe C. Thompson Conference Center, Un i vers ity of Texas at Austin, March 12-16, 1984. The workshop dealt with stochastic phenomena and sensi tivity in nonequilibrium systems from a macroscopic point of view. Durin9 the last few years it has been realized that the role of fluctuations is far less trivial in systems far from equilibrium than in systems under thermodynamic equilibrium condi tions. It was found that random fluctuations often are a determining factor for the state adopted by macroscopic systems and cannot be regarded as secondary effects of minor importance. Further, nonequilibrium systems are also very sensitive to small systematic changes in their environment. The main aims of the workshop were: i) to provide scientists with an occasion to acquaint themselves with the state of the art in fluctuation theory and sensitivity analysis; ii) to provide a forum for the presentation of recent advances in theory and experiment; iii) to bring toge ther theoreticians and experimentalists in order to delineate the major open problems and to formulate strategies to tackle these problems. The organizing committee of the workshop consisted of W. Horsthemke, O.K. Konde pudi, G. Dewel, G. Nicolis, I. Prigogine and L. Reichl.

Hydrodynamic Fluctuations in Fluids and Fluid Mixtures

Hydrodynamic Fluctuations in Fluids and Fluid Mixtures PDF Author: Jose M. Ortiz de Zarate
Publisher: Elsevier
ISBN: 9780080459431
Category : Science
Languages : en
Pages : 320

Book Description
This book deals with density, temperature, velocity and concentration fluctuations in fluids and fluid mixtures. The book first reviews thermal fluctuations in equilibrium fluids on the basis of fluctuating hydrodynamics. It then shows how the method of fluctuating hydrodynamics can be extended to deal with hydrodynamic fluctuations when the system is in a stationary nonequilibrium state. In contrast to equilibrium fluids where the fluctuations are generally short ranged unless the system is close to a critical point, fluctuations in nonequilibrium fluids are always long-ranged encompassing the entire system. The book provides the first comprehensive treatment of fluctuations in fluids and fluid mixtures brought out of equilibrium by the imposition of a temperature and concentration gradient but that are still in a macroscopically quiescent state. By incorporating appropriate boundary conditions in the case of fluid layers, it is shown how fluctuating hydrodynamics affects the fluctuations close to the onset of convection. Experimental techniques of light scattering and shadowgraphy for measuring nonequilibrium fluctuations are elucidated and the experimental results thus far reported in the literature are reviewed. · Systematic exposition of fluctuating hydrodynamics and its applications · First book on nonequilibrium fluctuations in fluids · Fluctuating Boussinesq equations and nonequilibrium fluids · Fluid layers and onset of convection · Rayleigh scattering and Brillouin scattering in fluids · Shadowgraph technique for measuring fluctuations · Fluctuations near hydrodynamic instabilities

Extended Irreversible Thermodynamics

Extended Irreversible Thermodynamics PDF Author: David Jou
Publisher: Springer Science & Business Media
ISBN: 3642974309
Category : Science
Languages : en
Pages : 320

Book Description
Classical irreversible thermodynamics, as developed by Onsager, Prigogine and many other authors, is based on the local-equilibrium hypothesis. Out of equilibrium, any system is assumed to depend locally on the same set of variables as when it is in eqUilibrium. This leads to a formal thermody namic structure identical to that of eqUilibrium: intensive parameters such as temperature, pressure and chemical potentials are well-defined quantities keeping their usual meaning, thermodynamic potentials are derived as Leg endre transformations and all equilibrium thermodynamic relations retain their validity. The theory based on this hypothesis has turned out to be very useful and has achieved a number of successes in many practical situations. of interest in going However, the recent decade has witnessed a surge beyond the classical formulation. There are several reasons for this. One of them is the development of experimental methods able to deal with the response of systems to high-frequency and short-wavelength perturbations, such as ultrasound propagation and light and neutron scattering. The ob served results have led to generalizations of the classical hydrodynamical theories, by including memory functions or generalized transport coefficients depending on the frequency and the wavevector. This field has generated impressive progress in non-equilibrium statistical mechanics, but for the moment it has not brought about a parallel development in non-equilibrium thermodynamics. An extension of thermodynamics compatible with gener alized hydrodynamics therefore appears to be a natural subject of research.

Thermodynamic Theory of Structure, Stability and Fluctuations

Thermodynamic Theory of Structure, Stability and Fluctuations PDF Author: P. Glansdorff
Publisher: John Wiley & Sons
ISBN:
Category : Science
Languages : en
Pages : 346

Book Description
Glossary of principal symbols