Catalytic Activation and Functionalisation of Light Alkanes PDF Download

Author: E.G. Derouane
Publisher: Springer Science & Business Media
ISBN: 9401709823
Category : Science
Languages : en
Pages : 482

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Book Description
Light alkanes tend to be resistant to many forms of activation. The horizontal approach of the present book covers homogeneous, heterogeneous and biological catalysis, thus allowing readers to gain an awareness of progress and ideas in research areas different from their own. The book contains both general chapters, giving an overview of the subject, and specialised contributions that deal with the details and state of the art. A specialist report is also included which gives a critical insight into current progress and discusses future prospects and major challenges. Audience: Newcomers and senior researchers in the field of alkane activation. The mixed theoretical and practical approach will be of interest to researchers and industrialists alike.

Author: Pedro J. Pérez
Publisher: Springer Science & Business Media
ISBN: 9048136970
Category : Science
Languages : en
Pages : 277

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Book Description
Over the past decade, much research effort has been devoted to the design and synthesis of new reagents and catalysts that can influence carbon-hydrogen bond activation, mainly because of the prospect that C−H activation could enable the conversion of cheap and abundant alkanes into valuable functionalized organic compounds. Alkane C-H Activation by Single-Site Metal Catalysis presents the current state-of-the-art development in the catalytic systems for the catalytic trans-formations of alkanes under homogeneous conditions. Chapter 1 offers a comprehensive summary of the main discoveries realized so far. Chapter 2 reviews the so-called electrophilic activation, initiated by Shulpín in the late 60s, and the base for the Catalytica system. Chapter 3 examines the catalytic borylation of alkanes, discovered by Hartwig, whereas chapter 4 provides an updated vision of the alkane dehydrogenation reaction. Chapter 5 covers the oxygenation of C-H bonds, a field of enormous interest with bioinorganic im-plications, and finally chapter 6 presents the functionalization of alkane C-H bonds by carbene or nitrene insertion. The history of C-H bond activation, and the current research described in this book, highlight the current research and present the reader with an outlook of this field which continues to be explored by an increasingly visionary and enthusiastic group of organic, organometallic, biological and physical chemists.

Author: Armando J. L. Pombeiro
Publisher: John Wiley & Sons
ISBN: 111937880X
Category : Science
Languages : en
Pages : 680

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Book Description
Presents state-of-the-art information concerning the syntheses of valuable functionalized organic compounds from alkanes, with a focus on simple, mild, and green catalytic processes Alkane Functionalization offers a comprehensive review of the state-of-the-art of catalytic functionalization of alkanes under mild and green conditions. Written by a team of leading experts on the topic, the book examines the latest research developments in the synthesis of valuable functionalized organic compounds from alkanes. The authors describe the various modes of interaction of alkanes with metal centres and examine theoxidative alkane functionalization upon C-O bond formation. They address the many types of mechanisms, discuss typical catalytic systems and highlight the strategies inspired by biological catalytic systems. The book also describes alkane functionalization upon C-heteroatom bond formation as well as oxidative and non-oxidative approaches. In addition, the book explores non-transition metal catalysts and metal-free catalytic systems and presents selected types of functionalization of sp3 C-H bonds pertaining to substrates other than alkanes. This important resource: Presents a guide to the most recent advances concerning the syntheses of valuable functionalized organic compounds from alkanes Contains information from leading experts on the topic Offers information on the catalytic functionalization of alkanes that allows for improved simplicity and sustainability compared to current multi-stage industrial processes Explores the challenges inherent with the application of alkanes as starting materials for syntheses of added value functionalized organic compounds Written for academic researchers and industrial scientists working in the fields of coordination chemistry, organometallic chemistry, catalysis, organic synthesis and green chemistry, Alkane Functionalization is an important resource for accessing the most up-to-date information available in the field of catalytic functionalization of alkanes.

Author: Armando J. L. Pombeiro
Publisher: Wiley
ISBN: 9781119379256
Category : Alkanes
Languages : en
Pages : 648

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Book Description
Alkane Functionalization: Introduction and Overview / Armando J L Pombeiro -- C-O Bond Formation. Hydroxylation and Other Oxygenation Reactions -- Activation and Oxidative Functionalization of Alkanes with Noble-Metal Catalysts: Molecular Mechanisms / Evgeniy G Chepaikin -- Alkane-Oxidizing Systems Based on Metal Complexes. Radical Versus Nonradical Mechanisms / Georgiy B Shul'pin -- Reactions of Alkyl Radicals in Aqueous Solutions / Dan Meyerstein -- C-H Bond Oxidation with Transition-Metal-Based Carbene Complexes / Bruno Dominelli, Anja C Lindhorst, Fritz E Kühn -- Alkane Oxidation with C-Scorpionate Metal Complexes / Luísa M D R S Martins -- Alkane Oxidation with Multinuclear Heterometallic Catalysts / Dmytro S Nesterov, Oksana V Nesterova, Armando J L Pombeiro -- Oxidative Functionalization of Methane on Heterogeneous Catalysts / Maricruz Sanchez-Sanchez, Johannes A Lercher -- Gas-Phase Oxidation of Alkanes / Fabrizio Cavani, Alessandro Chieregato, Jose M López Nieto, Jean-Marc M Millet -- Bioinspired Alkane Functionalization -- Recent Developments of Bioinspired Approaches to Functionalization of Light Alkanes / Alexander B Sorokin -- Regioselectivity of Non-heme Iron Catalysts for C-H Activation / Christian R Goldsmith -- Imine-based Iron and Manganese Complexes as Catalysts for Alkane Functionalization / Giorgio Olivo, Osvaldo Lanzalunga, Stefano Di Stefano -- Alkane Oxidation with Biologically Inspired Nonheme Iron Catalysts Based in the Triazacyclononane Ligand Scaffold / Miquel Costas -- The Nature of High-Valent Oxometal Intermediates of Iron-Aminopyridine Mediated Oxidations / Oleg Y Lyakin, Konstantin P Bryliakov, Evgenii P Talsi -- Selective Oxidation of Alkanes by Metallo-Monooxygenases and Their Nanobiomimetics / Chih-Cheng Liu, Yi-Fang Tsai, Wondemagegn H Wanna, Ravirala Ramu, Damodar Janmanchi, Sunney I Chan, Steve S-F Yu -- Alkane Oxidation with Vanadium and Copper Catalysts / Manas Sutradhar, Luísa M D R S Martins, M Fátima C Guedes da Silva, Armando J L Pombeiro -- C-B, C-C and C-N Bond Formation -- Catalytic Borylation of Methane: Combining Computational and High-Throughput Screening Approaches to Discover a New Catalyst / Pavel Zatsepin, Dieter Sorsche, Seihwan Ahn, Mu-Hyun Baik, Daniel J Mindiola -- Alkane Carbonylation and Carbene Insertion Reactions / Ana M Faisca Phillips, Armando J L Pombeiro -- Catalytic Alkane Amidation and Related Reactions / Dmytro S Nesterov, Luís M T Frija, Armando J L Pombeiro, Maximilian N Kopylovich -- Dehydrogenation Reactions -- Oxidative and Nonoxidative Routes to Alkane Dehydrogenation / Jay A Labinger -- Dehydrogenation of Alkanes Using Molecular Catalysts / Huaquan Fang, Guixia Liu, Zheng Huang -- Unconventional Systems -- Nontransition Metal Catalyzed Oxidation of Alkanes with Peroxides / Maxim L Kuznetsov -- Metal-Free Functionalization of Alkanes / Jincan Zhao, Jianlin Han -- Alkane Functionalization under Unconventional Conditions: in Ionic Liquid, in Supercritical CO2, and Microwave Assisted / Ana P C Ribeiro, Elisabete C B A Alegria, António Palavra, Armando J L Pombeiro -- Noncovalent Interactions in Alkane Chemistry / Kamran T Mahmudov, M Fátima C Guedes da Silva, Fedor I Zubkov, Armando J L Pombeiro -- Alkane Complexation / Robert H Crabtree -- Alkane-Related C-H Bond Activation and Functionalization of Aliphatic Amines / Christian Bruneau, Mathieu Achard.

Author: National Academies of Sciences, Engineering, and Medicine
Publisher: National Academies Press
ISBN: 0309444799
Category : Science
Languages : en
Pages : 137

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Book Description
A decade ago, the U.S. chemical industry was in decline. Of the more than 40 chemical manufacturing plants being built worldwide in the mid-2000s with more than $1 billion in capitalization, none were under construction in the United States. Today, as a result of abundant domestic supplies of affordable natural gas and natural gas liquids resulting from the dramatic rise in shale gas production, the U.S. chemical industry has gone from the world's highest-cost producer in 2005 to among the lowest-cost producers today. The low cost and increased supply of natural gas and natural gas liquids provides an opportunity to discover and develop new catalysts and processes to enable the direct conversion of natural gas and natural gas liquids into value-added chemicals with a lower carbon footprint. The economic implications of developing advanced technologies to utilize and process natural gas and natural gas liquids for chemical production could be significant, as commodity, intermediate, and fine chemicals represent a higher-economic-value use of shale gas compared with its use as a fuel. To better understand the opportunities for catalysis research in an era of shifting feedstocks for chemical production and to identify the gaps in the current research portfolio, the National Academies of Sciences, Engineering, and Medicine conducted an interactive, multidisciplinary workshop in March 2016. The goal of this workshop was to identify advances in catalysis that can enable the United States to fully realize the potential of the shale gas revolution for the U.S. chemical industry and, as a result, to help target the efforts of U.S. researchers and funding agencies on those areas of science and technology development that are most critical to achieving these advances. This publication summarizes the presentations and discussions from the workshop.

Author: Pierre H. Dixneuf
Publisher: Springer
ISBN: 3319246305
Category : Science
Languages : en
Pages : 264

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Book Description
The series Topics in Organometallic Chemistry presents critical overviews of research results in organometallic chemistry. As our understanding of organometallic structure, properties and mechanisms increases, new ways are opened for the design of organometallic compounds and reactions tailored to the needs of such diverse areas as organic synthesis, medical research, biology and materials science. Thus the scope of coverage includes a broad range of topics of pure and applied organometallic chemistry, where new breakthroughs are being achieved that are of significance to a larger scientific audience. The individual volumes of Topics in Organometallic Chemistry are thematic. Review articles are generally invited by the volume editors. All chapters from Topics in Organometallic Chemistry are published OnlineFirst with an individual DOI. In references, Topics in Organometallic Chemistry is abbreviated as Top Organomet Chem and cited as a journal.

Author: Sadasivan Shankar
Publisher: Springer Nature
ISBN: 3030187780
Category : Technology & Engineering
Languages : en
Pages : 1344

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Book Description
This book provides a broad and nuanced overview of the achievements and legacy of Professor William (“Bill”) Goddard in the field of computational materials and molecular science. Leading researchers from around the globe discuss Goddard’s work and its lasting impacts, which can be seen in today’s cutting-edge chemistry, materials science, and biology techniques. Each section of the book closes with an outline of the prospects for future developments. In the course of a career spanning more than 50 years, Goddard’s seminal work has led to dramatic advances in a diverse range of science and engineering fields. Presenting scientific essays and reflections by students, postdoctoral associates, collaborators and colleagues, the book describes the contributions of one of the world’s greatest materials and molecular scientists in the context of theory, experimentation, and applications, and examines his legacy in each area, from conceptualization (the first mile) to developments and extensions aimed at applications, and lastly to de novo design (the last mile). Goddard’s passion for science, his insights, and his ability to actively engage with his collaborators in bold initiatives is a model for us all. As he enters his second half-century of scientific research and education, this book inspires future generations of students and researchers to employ and extend these powerful techniques and insights to tackle today’s critical problems in biology, chemistry, and materials. Examples highlighted in the book include new materials for photocatalysts to convert water and CO2 into fuels, novel catalysts for the highly selective and active catalysis of alkanes to valuable organics, simulating the chemistry in film growth to develop two-dimensional functional films, and predicting ligand–protein binding and activation to enable the design of targeted drugs with minimal side effects.

Author: A.E. Shilov
Publisher: Springer Science & Business Media
ISBN: 9781402004209
Category : Science
Languages : en
Pages : 556

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Book Description
hemistry is the science about breaking and forming of bonds between atoms. One of the most important processes for organic chemistry is breaking bonds C–H, as well as C–C in various compounds, and primarily, in hydrocarbons. Among hydrocarbons, saturated hydrocarbons, alkanes (methane, ethane, propane, hexane etc. ), are especially attractive as substrates for chemical transformations. This is because, on the one hand, alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for chemical industry. On the other hand, these substances are known to be the less reactive organic compounds. Saturated hydrocarbons may be called the “noble gases of organic chemistry” and, if so, the first representative of their family – methane – may be compared with extremely inert helium. As in all comparisons, this parallel between noble gases and alkanes is not fully accurate. Indeed the transformations of alkanes, including methane, have been known for a long time. These reactions involve the interaction with molecular oxygen from air (burning – the main source of energy!), as well as some mutual interconversions of saturated and unsaturated hydrocarbons. However, all these transformations occur at elevated temperatures (higher than 300–500 °C) and are usually characterized by a lack of selectivity. The conversion of alkanes into carbon dioxide and water during burning is an extremely valuable process – but not from a chemist viewpoint.

Author: A.E. Shilov
Publisher: Springer Science & Business Media
ISBN: 0792361016
Category : Science
Languages : en
Pages : 551

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Book Description
This monograph is devoted to the activation and various transformations of saturated hydrocarbons (alkanes), i.e. reactions accompanied by the C-H and C-C bond cleavage. Alkanes are the main constituents of oil and natural gas, and consequently are the principal feedstocks for the chemical industry. On the other hand, these substances are known to be the least reactive organic compounds. Special attention is paid to the recently found alkane activations in the presence of metal complexes, which are described in more detail. In addition to the reactions of saturated hydrocarbons which are the main topic of this book, the activation of C-H bonds in arenes and even olefins and acetylenes are considered. The monograph will be useful not only for those who are interested in the activation of alkanes and other hydrocarbons by metal complexes, but also for specialists in homogeneous and heterogeneous catalysis, petrochemistry, and organometallic chemistry. Some parts of the monograph will be of interest for specialists in inorganic and organic chemistry, theoretical chemistry, biochemistry and even biology, and also for those who work in the petrochemical industry, industrial organic synthesis and biotechnology.

Author: E.G. Derouane
Publisher: Springer Science & Business Media
ISBN: 9401143293
Category : Science
Languages : en
Pages : 497

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Book Description
Catalysts are central in modern industrial chemistry and there is an urgent need to develop new catalysts. Such a rapid pace of development brings with it a new set of challenges at all levels of research, from synthesis and characterization to testing and modelling. This book reviews the current status of combinatorial catalysis, scientific catalyst design techniques, methods for preparing inorganic combinatorial libraries, experimental design methods, data processing, system modelling an simulation, and catalyst testing. The individual contributions reveal the development of high throughput catalyst design and test methods and identify the main challenges in the field, including new catalyst preparation techniques, rapid performance evaluation, and new microreactor configurations. Readership: All those working in catalytic process analysis and development. The extensive review of catalysis principles is especially relevant for postgraduate students seeking to pursue studies in catalysis.