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Author: Popielawski J Publisher: World Scientific ISBN: 9814569275 Category : Languages : en Pages : 440
Book Description
The proceedings discuss the theoretical methods used to describe a chemical system which is far from the equilibrium state, and this is illustrated by selected applications. Special attention is paid to very fast chemical reactions and systems in which external or internal noise is present. In particular, the following topics are covered:-the generalized Boltzmann/ Enskog equation for nonequilibrium systems,-stochastic methods for description of noise in chemical systems,-numerical simulations of systems far from equilibrium.
Author: Popielawski J Publisher: World Scientific ISBN: 9814569275 Category : Languages : en Pages : 440
Book Description
The proceedings discuss the theoretical methods used to describe a chemical system which is far from the equilibrium state, and this is illustrated by selected applications. Special attention is paid to very fast chemical reactions and systems in which external or internal noise is present. In particular, the following topics are covered:-the generalized Boltzmann/ Enskog equation for nonequilibrium systems,-stochastic methods for description of noise in chemical systems,-numerical simulations of systems far from equilibrium.
Author: Yasumasa Nishiura Publisher: American Mathematical Soc. ISBN: 9780821826256 Category : Mathematics Languages : en Pages : 340
Book Description
This book is devoted to the study of evolution of nonequilibrium systems. Such a system usually consists of regions with different dominant scales, which coexist in the space-time where the system lives. In the case of high nonuniformity in special direction, one can see patterns separated by clearly distinguishable boundaries or interfaces. The author considers several examples of nonequilibrium systems. One of the examples describes the invasion of the solid phase into the liquidphase during the crystallization process. Another example is the transition from oxidized to reduced states in certain chemical reactions. An easily understandable example of the transition in the temporal direction is a sound beat, and the author describes typical patterns associated with thisphenomenon. The main goal of the book is to present a mathematical approach to the study of highly nonuniform systems and to illustrate it with examples from physics and chemistry. The two main theories discussed are the theory of singular perturbations and the theory of dissipative systems. A set of carefully selected examples of physical and chemical systems nicely illustrates the general methods described in the book.
Author: C. Vidal Publisher: Springer Science & Business Media ISBN: 3642701965 Category : Science Languages : en Pages : 260
Book Description
Markedly apart from elementary particle physics, another current has been building up and cont i nuous ly growi ng within contemporary phys i cs for severa 1 decades, and even expanding into many other disciplines, especially chemistry, biology and, quite recently, economics. Several reasons account for this: presumably the most impor tant one lies in the fact that, whatever the specific problem, model or material concerned, the same basic mathematical features are always involved. In this way, a general phenomenology has emerged which, unlike thermodynamics, is no longer depen dent upon the details or specifics: what largely prevails is the nonlinear charac ter of the underlying dynamics. Perhaps we are witnessing the emergence of a "non linear physics"--In a way similar to the birth of "quantum physics" in the twen ties - a physics which deals with the general behaviour of systems, whatever they are or may be. Over the past fifteen years, chemical systems evolving sufficiently far from equilibrium have proved to be particularly well fitted to experimental research on nonlinear behaviour: oscillation, multistability, birhythmicity, chaotic evolution, spatial self-organization and hysteresis are displayed by chemical reactions whose number is growing each year. In this volume are collected the lectures, communica tions and posters (abstracts) presented at an international meeting entitled: "Non-Equilibrium Dynamics in Chemical Systems", held in Bordeaux (France), Septem ber 3 rd-lth, 1984.
Author: John Ross Publisher: Springer Science & Business Media ISBN: 3540745556 Category : Science Languages : en Pages : 207
Book Description
This book deals with the formulation of the thermodynamics of chemical and other systems far from equilibrium. It contains applications to non-equilibrium stationary states and approaches to such states, systems with multiple stationary states, stability and equi-stability conditions, reaction diffusion systems, transport properties, and electrochemical systems. The theoretical treatment is complemented by experimental results to substantiate the formulation.
Author: R. P. Rastogi Publisher: Elsevier ISBN: 9780080551807 Category : Science Languages : en Pages : 356
Book Description
Introduction to Non-equilibrium Physical Chemistry presents a critical and comprehensive account of Non-equilibrium Physical Chemistry from theoretical and experimental angle. It covers a wide spectrum of non-equilibrium phenomena from steady state close to equilibrium to non-linear region involving transition to bistability, temporal oscillations, spatio-temporal oscillations and finally to far from equilibrium phenomena such as complex pattern formation, dynamic instability at interfaces, Chaos and complex growth phenomena (fractals) in Physico-chemical systems. Part I of the book deals with theory and experimental studies concerning transport phenomena in membranes (Thermo-osmosis,Electroosmotic ) and in continuous systems (Thermal diffusion,Soret effect) close to equilibrium Experimental tests provide insight into the domain of validity of Non-equilibrium Thermodynamics ,which is the major theoretical tool for this region. Later developments in Extended Irreversible Thermodynamics and Non-equilibrium Molecular dynamics have been discussed in the Appendix. Part II deals with non-linear steady states and bifurcation to multistability, temporal and spatio- temporal oscillations (Chemical waves). Similarly Part II deals with more complex phenomena such as Chaos and fractal growth occurring in very far from equilibrium region. Newer mathematical techniques for investigating such phenomena along with available experimental studies. Part IV deals with analogous non-equilibrium phenomena occurring in the real systems (Socio-political, Finance and Living systems etc.) for which physico-chemical systems discussed in earlier chapters provide a useful model for development of theories based on non-linear science and science of complexity. The book provides a critical account of theoretical studies on non-equilibrium phenomenon from region close to equilibrium to far equilibrium Experimental studies have been reported which provide test of the theories and their limitations Impacts of the concepts developed in non-equilibrium Physical Chemistry in sociology, economics and other social science and living systems has been discussed
Author: Jose E. Wesfreid Publisher: Springer Science & Business Media ISBN: 3642738613 Category : Science Languages : en Pages : 431
Book Description
Macroscopic physics provides us with a great variety of pattern-forming systems displaying propagation phenomena, from reactive fronts in combustion, to wavy structures in convection and to shear flow instabilities in hydrodynamics. These proceedings record progress in this rapidly expanding field. The contributions have the following major themes: - The problems of velocity selection and front morphology of propagating interfaces in multiphase media, with emphasis on recent theoretical and experimental results on dendritic crystal growth, Saffman-Taylor fingering, directional solidification and chemical waves. - The "unfolding" of large-scale, low-frequency behavior in weakly confined homogeneous systems driven far from equilibrium, and more specifically, the envelope approach to the mathematical description of textures in different cases: steady cells, propagating waves, structural defects, and phase instabilities. - The implications of the presence of global downstream transport in open flows for the nature, convective or absolute, of shear flow instabilities, with applications to real boundary layer flows or shear layers, as reported in contributions covering experimental situations of fundamental and/or engineering interest.
Author: A. Pacault Publisher: Springer Science & Business Media ISBN: 3642672620 Category : Mathematics Languages : en Pages : 188
Book Description
This volume gathers most of the lectures and communications presented at the meeting t held in Bordeaux from the 27th to the 29 h of September and entitled "Far from equi librium : instabilities and structures". This meeting is part of a series of seve ral other interdisciplinary conferences such as Elmau 1972, London 1974, Dortmund 1976, Elmau 1977, Tokyo 1978. The old science classification scheme proposed by Auguste Comte tends to be eve ry day a bit more blurred out: one gives here, if needed, one additional illustra tion of this trend. The three key words "far from equilibrium", "instabilities" and "structures" best illustrate the new concepts which emerge from the description of the dynamics of various systems relevant to many different research areas. Laser emission, chemical reactions, fluid motions, exhibit very particular phenomena when, under appropriate external action,they occur far from equilibrium. These proceedings include the experimental description of such phenomena as well as theoretical at tempts in understanding them. Most of the topics investigated here belong to the domains of physics and chemistry but one should be careful not to underestimate the underlying potential biological interest. If the study of simple systems (e. g. , described by a few variables) has been qui te successful for several centuries, the recent bearing of our attention on complex systems constitutes a genuine epistemological breakthrough bridging the gap which used to exist between the sciences and the humanism.
Author: V. Parmon Publisher: Elsevier ISBN: 9780080931968 Category : Science Languages : en Pages : 340
Book Description
Thermodynamics of Non-Equilibrium Processes for Chemists with a Particular Application to Catalysis consists of materials adapted from lectures on the thermodynamics of nonequilibrium processes that have been taught at the Department of Natural Sciences of Novosibirsk State University since 1995. The thermodynamics of nonequilibrium processes traditionally required students to have a strong background in physics. However, the materials featured in this volume allow anyone with knowledge in classical thermodynamics of equilibrium processes and traditional chemical kinetics to understand the subject. Topics discussed include systems in the thermodynamics of irreversible processes; thermodynamics of systems that are close to and far from equilibrium; thermodynamics of catalysts; the application of nonequilibrium thermodynamics to material science; and the relationship between entropy and information. This book will be helpful for research into complex chemical transformations, particularly catalytic transformations. Applies simple approaches of non-equilibrium thermodynamics to analyzing properties of chemically reactive systems Covers systems far from equilibrium, allowing the consideration of most chemically reactive systems of a chemical or biological nature This approach resolves many complicated problems in the teaching of chemical kinetics
Author: Popielawski J
Author: Popielawski J
Author: 
Author: J. Popielawski
Author: Yasumasa Nishiura
Author: C. Vidal
Author: John Ross
Author: R. P. Rastogi
Author: Jose E. Wesfreid
Author: A. Pacault
Author: V. Parmon